TY  - JOUR
AU  - Radulović, Dragan
AU  - Terzić, Anja
AU  - Stojanović, Jovica
AU  - Jovanović, Vladimir
AU  - Todorović, Dejan
AU  - Ivošević, Branislav
PY  - 2024
UR  - http://rims.institutims.rs/handle/123456789/816
AB  - Smelting used to be less efficient; therefore, wastes obtained from historical processing at smelter plants usually contain certain quantities of valuable metals. Upon the extraction of useful metal elements, metallurgical slag can be repurposed as an alternative mineral raw material in the building sector. A case study was conducted, which included an investigation of the physico-chemical, mineralogical, and microstructural properties of Pb–Zn slag found at the historic landfill near the Topilnica Veles smelter in North Macedonia. The slag was sampled using drill holes. The mineralogical and microstructural analysis revealed that Pb–Zn slag is a very complex and inhomogeneous alternative raw material with utilizable levels of metals, specifically Pb (2.3 wt.%), Zn (7.1 wt.%), and Ag (27.5 ppm). Crystalline mineral phases of wurtzite, sphalerite, galena, cerussite, akermanite, wüstite, monticellite, franklinite, and zincite were identified in the analyzed samples. The slag’s matrix consisted of alumino-silicates, amorphous silicates, and mixtures of spinel and silicates. Due to the economic potential of Pb, Zn, and Ag extraction, the first stage of reutilization will be to transform metal concentrates into their collective concentrate, from which the maximum amount of these crucial components can be extracted. This procedure will include combination of gravity concentration and separation techniques. The next step is to assess the Pb–Zn slag’s potential applications in civil engineering, based on its mineralogical and physico-mechanical properties. Alumino-silicates present in Pb–Zn slag, which contain high concentrations of SiO2, Al2O3, CaO, and Fe2O3, are suitable for use in cementitious building composites. The goal of this research is to suggest a solution by which to close the circle of slag’s reutilization in terms of zero waste principles. It is therefore critical to thoroughly investigate the material, the established methods and preparation processes, and the ways of concentrating useful components into commercial products.
PB  - MDPI
T2  - Sustainability
T1  - Reapplication Potential of Historic Pb–Zn Slag with Regard to Zero Waste Principles
IS  - 2
VL  - 16
DO  - 10.3390/su16020720
ER  - 

@article{
author = "Radulović, Dragan and Terzić, Anja and Stojanović, Jovica and Jovanović, Vladimir and Todorović, Dejan and Ivošević, Branislav",
year = "2024",
abstract = "Smelting used to be less efficient; therefore, wastes obtained from historical processing at smelter plants usually contain certain quantities of valuable metals. Upon the extraction of useful metal elements, metallurgical slag can be repurposed as an alternative mineral raw material in the building sector. A case study was conducted, which included an investigation of the physico-chemical, mineralogical, and microstructural properties of Pb–Zn slag found at the historic landfill near the Topilnica Veles smelter in North Macedonia. The slag was sampled using drill holes. The mineralogical and microstructural analysis revealed that Pb–Zn slag is a very complex and inhomogeneous alternative raw material with utilizable levels of metals, specifically Pb (2.3 wt.%), Zn (7.1 wt.%), and Ag (27.5 ppm). Crystalline mineral phases of wurtzite, sphalerite, galena, cerussite, akermanite, wüstite, monticellite, franklinite, and zincite were identified in the analyzed samples. The slag’s matrix consisted of alumino-silicates, amorphous silicates, and mixtures of spinel and silicates. Due to the economic potential of Pb, Zn, and Ag extraction, the first stage of reutilization will be to transform metal concentrates into their collective concentrate, from which the maximum amount of these crucial components can be extracted. This procedure will include combination of gravity concentration and separation techniques. The next step is to assess the Pb–Zn slag’s potential applications in civil engineering, based on its mineralogical and physico-mechanical properties. Alumino-silicates present in Pb–Zn slag, which contain high concentrations of SiO2, Al2O3, CaO, and Fe2O3, are suitable for use in cementitious building composites. The goal of this research is to suggest a solution by which to close the circle of slag’s reutilization in terms of zero waste principles. It is therefore critical to thoroughly investigate the material, the established methods and preparation processes, and the ways of concentrating useful components into commercial products.",
publisher = "MDPI",
journal = "Sustainability",
title = "Reapplication Potential of Historic Pb–Zn Slag with Regard to Zero Waste Principles",
number = "2",
volume = "16",
doi = "10.3390/su16020720"
}

Radulović, D., Terzić, A., Stojanović, J., Jovanović, V., Todorović, D.,& Ivošević, B.. (2024). Reapplication Potential of Historic Pb–Zn Slag with Regard to Zero Waste Principles. in Sustainability
MDPI., 16(2).
https://doi.org/10.3390/su16020720

Radulović D, Terzić A, Stojanović J, Jovanović V, Todorović D, Ivošević B. Reapplication Potential of Historic Pb–Zn Slag with Regard to Zero Waste Principles. in Sustainability. 2024;16(2).
doi:10.3390/su16020720 .

Radulović, Dragan, Terzić, Anja, Stojanović, Jovica, Jovanović, Vladimir, Todorović, Dejan, Ivošević, Branislav, "Reapplication Potential of Historic Pb–Zn Slag with Regard to Zero Waste Principles" in Sustainability, 16, no. 2 (2024),
https://doi.org/10.3390/su16020720 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Paunović, Vesna
AU  - Stojanović, Jovica
PY  - 2024
UR  - http://rims.institutims.rs/handle/123456789/807
AB  - The primary objective of this study was to look into the role of titanium dioxide in the production of corundum-based mortars, with a focus on finding the optimal mortar composition for achieving improved mechanical and dielectric performances. Changes in the mix design (different binders, different additive dosages), as well as their effects on the hydration pathway, chemical bonds, phase modifications, and microstructure, were examined. These findings were then correlated to the designed mortars' mechanical strengths and dielectric properties. Experimental mortars were produced with binders made from ordinary Portland cement, high alumina cement, and their mixtures, and corundum as aggregate. Titanium dioxide was employed as an additive (3 and 5 wt%). Nine different mortars were submitted for comprehensive mineralogical and microstructural characterization upon curing and solidification. The compressive and flexural strengths were monitored throughout the 28-day period. The dielectric constant (εr), dielectric loss tangent (tan δ), and electrical resistivity (ρ) were measured over a frequency range of 100 Hz to 1 MHz. XRD analysis highlighted the appearance of mayenite as a dielectric-prone phase in the samples doped with titanium dioxide. Differential thermal analysis and FTIR spectroscopy identified a higher amount of extra-low crystalline phase in OPC and HAC mortars with TiO2 addition, which accelerated hydration mechanisms, created a surplus of hydration products and made a more compact cement matrix. TiO2 added in 3 wt% amount led to higher mechanical strengths in OPC-based mortars, while it improved the dielectric properties of HAC mortars.
PB  - Elsevier Ltd
T2  - Construction and Building Materials
T1  - Effect of the titanium-dioxide addition on the structural, dielectric, and mechanical properties of different cement-based mortars with corundum aggregate
VL  - 412
DO  - 10.1016/j.conbuildmat.2023.134847
ER  - 

@article{
author = "Terzić, Anja and Paunović, Vesna and Stojanović, Jovica",
year = "2024",
abstract = "The primary objective of this study was to look into the role of titanium dioxide in the production of corundum-based mortars, with a focus on finding the optimal mortar composition for achieving improved mechanical and dielectric performances. Changes in the mix design (different binders, different additive dosages), as well as their effects on the hydration pathway, chemical bonds, phase modifications, and microstructure, were examined. These findings were then correlated to the designed mortars' mechanical strengths and dielectric properties. Experimental mortars were produced with binders made from ordinary Portland cement, high alumina cement, and their mixtures, and corundum as aggregate. Titanium dioxide was employed as an additive (3 and 5 wt%). Nine different mortars were submitted for comprehensive mineralogical and microstructural characterization upon curing and solidification. The compressive and flexural strengths were monitored throughout the 28-day period. The dielectric constant (εr), dielectric loss tangent (tan δ), and electrical resistivity (ρ) were measured over a frequency range of 100 Hz to 1 MHz. XRD analysis highlighted the appearance of mayenite as a dielectric-prone phase in the samples doped with titanium dioxide. Differential thermal analysis and FTIR spectroscopy identified a higher amount of extra-low crystalline phase in OPC and HAC mortars with TiO2 addition, which accelerated hydration mechanisms, created a surplus of hydration products and made a more compact cement matrix. TiO2 added in 3 wt% amount led to higher mechanical strengths in OPC-based mortars, while it improved the dielectric properties of HAC mortars.",
publisher = "Elsevier Ltd",
journal = "Construction and Building Materials",
title = "Effect of the titanium-dioxide addition on the structural, dielectric, and mechanical properties of different cement-based mortars with corundum aggregate",
volume = "412",
doi = "10.1016/j.conbuildmat.2023.134847"
}

Terzić, A., Paunović, V.,& Stojanović, J.. (2024). Effect of the titanium-dioxide addition on the structural, dielectric, and mechanical properties of different cement-based mortars with corundum aggregate. in Construction and Building Materials
Elsevier Ltd., 412.
https://doi.org/10.1016/j.conbuildmat.2023.134847

Terzić A, Paunović V, Stojanović J. Effect of the titanium-dioxide addition on the structural, dielectric, and mechanical properties of different cement-based mortars with corundum aggregate. in Construction and Building Materials. 2024;412.
doi:10.1016/j.conbuildmat.2023.134847 .

Terzić, Anja, Paunović, Vesna, Stojanović, Jovica, "Effect of the titanium-dioxide addition on the structural, dielectric, and mechanical properties of different cement-based mortars with corundum aggregate" in Construction and Building Materials, 412 (2024),
https://doi.org/10.1016/j.conbuildmat.2023.134847 . .

TY  - CONF
AU  - Radulović, Dragan
AU  - Jovanović, Vladimir
AU  - Todorović, Dejan
AU  - Ivošević, Branislav
AU  - Stojanović, Jovica
AU  - Milićević, Sonja
AU  - Terzić, Anja
PY  - 2023
UR  - http://rims.institutims.rs/handle/123456789/574
AB  - According to earlier physical-chemical and mineralogical analysis, slag from "Topionica"- Veles (Northern Macedonia) represents a potentially important raw resource. It is an inhomogeneous raw material with considerable nonferrous metal content, particularly Pb, Zn, Cu, and Ag (considered as a precious metal). This technogenic resource's mineralogical analysis revealed a very complex composition: amorphous phase, lead alloys, zinc alloys, wüstite (FeO), sphalerite, galena, cerussite, elemental silver, elemental copper, elemental iron, magnetite, spinel, rutile, hematite, troilite (FeS). The most abundant phase is an amorphous phase (glassy matrix) composed of spinel, silicate, and mixed (spinel-silicate). The sample has substantially less wüstite, that appears as skeletal inclusions in the glassy matrix. SEM investigation revealed the presence of Fe-Mn-Zn spinels in the Pb-Zn slag, as well as Pb and Zn alloys. These alloys are primarily composed of Cu. The grains of these phases are up to 100μm appearing as inclusions (usually as complex inclusions with a glassy matrix of elemental iron and wüstite). Grains bigger than 100μm in length are typically free or have simple inclusions. The biggest grains in the aforementioned stages have diameters of up to 300μm. The mineralogical study revealed that the Pb-Zn slag is a very complex raw material. It is required to investigate it in detail and establish the methods in which it can be done in order to value it and eventually apply it. Every stage of the preparation process has to be accompanied by numerous analyzes that will indicate the relevance of the preparation process and ways of concentrating useful components into commercial products.
C3  - Serbian Ceramic Society Conference “Advanced Ceramic and Application XI – New frontiers in multifunctional material science and processing”, Book of Abstracts, Belgrade, Serbia
T1  - Technical features of Pb-Zn slag that allow its valorization and application
SP  - 81
UR  - https://hdl.handle.net/21.15107/rcub_rims_574
ER  - 

@conference{
author = "Radulović, Dragan and Jovanović, Vladimir and Todorović, Dejan and Ivošević, Branislav and Stojanović, Jovica and Milićević, Sonja and Terzić, Anja",
year = "2023",
abstract = "According to earlier physical-chemical and mineralogical analysis, slag from "Topionica"- Veles (Northern Macedonia) represents a potentially important raw resource. It is an inhomogeneous raw material with considerable nonferrous metal content, particularly Pb, Zn, Cu, and Ag (considered as a precious metal). This technogenic resource's mineralogical analysis revealed a very complex composition: amorphous phase, lead alloys, zinc alloys, wüstite (FeO), sphalerite, galena, cerussite, elemental silver, elemental copper, elemental iron, magnetite, spinel, rutile, hematite, troilite (FeS). The most abundant phase is an amorphous phase (glassy matrix) composed of spinel, silicate, and mixed (spinel-silicate). The sample has substantially less wüstite, that appears as skeletal inclusions in the glassy matrix. SEM investigation revealed the presence of Fe-Mn-Zn spinels in the Pb-Zn slag, as well as Pb and Zn alloys. These alloys are primarily composed of Cu. The grains of these phases are up to 100μm appearing as inclusions (usually as complex inclusions with a glassy matrix of elemental iron and wüstite). Grains bigger than 100μm in length are typically free or have simple inclusions. The biggest grains in the aforementioned stages have diameters of up to 300μm. The mineralogical study revealed that the Pb-Zn slag is a very complex raw material. It is required to investigate it in detail and establish the methods in which it can be done in order to value it and eventually apply it. Every stage of the preparation process has to be accompanied by numerous analyzes that will indicate the relevance of the preparation process and ways of concentrating useful components into commercial products.",
journal = "Serbian Ceramic Society Conference “Advanced Ceramic and Application XI – New frontiers in multifunctional material science and processing”, Book of Abstracts, Belgrade, Serbia",
title = "Technical features of Pb-Zn slag that allow its valorization and application",
pages = "81",
url = "https://hdl.handle.net/21.15107/rcub_rims_574"
}

Radulović, D., Jovanović, V., Todorović, D., Ivošević, B., Stojanović, J., Milićević, S.,& Terzić, A.. (2023). Technical features of Pb-Zn slag that allow its valorization and application. in Serbian Ceramic Society Conference “Advanced Ceramic and Application XI – New frontiers in multifunctional material science and processing”, Book of Abstracts, Belgrade, Serbia, 81.
https://hdl.handle.net/21.15107/rcub_rims_574

Radulović D, Jovanović V, Todorović D, Ivošević B, Stojanović J, Milićević S, Terzić A. Technical features of Pb-Zn slag that allow its valorization and application. in Serbian Ceramic Society Conference “Advanced Ceramic and Application XI – New frontiers in multifunctional material science and processing”, Book of Abstracts, Belgrade, Serbia. 2023;:81.
https://hdl.handle.net/21.15107/rcub_rims_574 .

Radulović, Dragan, Jovanović, Vladimir, Todorović, Dejan, Ivošević, Branislav, Stojanović, Jovica, Milićević, Sonja, Terzić, Anja, "Technical features of Pb-Zn slag that allow its valorization and application" in Serbian Ceramic Society Conference “Advanced Ceramic and Application XI – New frontiers in multifunctional material science and processing”, Book of Abstracts, Belgrade, Serbia (2023):81,
https://hdl.handle.net/21.15107/rcub_rims_574 .

TY  - JOUR
AU  - Terzić, Anja
AU  - Vasić, Milica
AU  - Stojanović, Jovica
AU  - Pavlović, Vladimir
AU  - Radojević, Zagorka
PY  - 2023
UR  - http://rims.institutims.rs/handle/123456789/485
AB  - Phyllosilicate mineral pyrophyllite is predominantly used in the ceramic industry because it exhibits high refractoriness. Due to its thermal transformation into mullite, pyrophyllite is stable at elevated temperatures, making it a suitable mineral additive for refractory non-shaped materials and various ceramic shaped products. In this study, pyrophyllite is employed as 50 % clay replacement in the ceramics and up to 30 % cement replacement in mortars. Physico-mechanical properties were investigated. The firing shrinkage in the ceramics treated at 1200°C was reduced by pyrophyllite addition. Pyrophyllite acted as additional pozzolana during cement hydration. Within the microstructure, it formed micro-reinforcement in the shape of crystalline folia, which improves the mechanical properties of ordinary Portland cement, high aluminate cement, and blended cement mortars. The investigation proved the efficiency and suitability of pyrophyllite employed as a substitution for clay in ceramics and a cement replacement in mortars.
T2  - Science of Sintering 2023 OnLine-First Issue 00
T1  - Application of pyrophyllite in high-temperature treated building materials
SP  - 14
DO  - 10.2298/SOS220610014T
ER  - 

@article{
author = "Terzić, Anja and Vasić, Milica and Stojanović, Jovica and Pavlović, Vladimir and Radojević, Zagorka",
year = "2023",
abstract = "Phyllosilicate mineral pyrophyllite is predominantly used in the ceramic industry because it exhibits high refractoriness. Due to its thermal transformation into mullite, pyrophyllite is stable at elevated temperatures, making it a suitable mineral additive for refractory non-shaped materials and various ceramic shaped products. In this study, pyrophyllite is employed as 50 % clay replacement in the ceramics and up to 30 % cement replacement in mortars. Physico-mechanical properties were investigated. The firing shrinkage in the ceramics treated at 1200°C was reduced by pyrophyllite addition. Pyrophyllite acted as additional pozzolana during cement hydration. Within the microstructure, it formed micro-reinforcement in the shape of crystalline folia, which improves the mechanical properties of ordinary Portland cement, high aluminate cement, and blended cement mortars. The investigation proved the efficiency and suitability of pyrophyllite employed as a substitution for clay in ceramics and a cement replacement in mortars.",
journal = "Science of Sintering 2023 OnLine-First Issue 00",
title = "Application of pyrophyllite in high-temperature treated building materials",
pages = "14",
doi = "10.2298/SOS220610014T"
}

Terzić, A., Vasić, M., Stojanović, J., Pavlović, V.,& Radojević, Z.. (2023). Application of pyrophyllite in high-temperature treated building materials. in Science of Sintering 2023 OnLine-First Issue 00, 14.
https://doi.org/10.2298/SOS220610014T

Terzić A, Vasić M, Stojanović J, Pavlović V, Radojević Z. Application of pyrophyllite in high-temperature treated building materials. in Science of Sintering 2023 OnLine-First Issue 00. 2023;:14.
doi:10.2298/SOS220610014T .

Terzić, Anja, Vasić, Milica, Stojanović, Jovica, Pavlović, Vladimir, Radojević, Zagorka, "Application of pyrophyllite in high-temperature treated building materials" in Science of Sintering 2023 OnLine-First Issue 00 (2023):14,
https://doi.org/10.2298/SOS220610014T . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Dojčinović, Marina
AU  - Miličić, Ljiljana
AU  - Stojanović, Jovica
AU  - Radojević, Zagorka
PY  - 2021
UR  - http://rims.institutims.rs/handle/123456789/399
AB  - Micro-silica is a highly efficient mineral additive whose role is reflected in improvements of microstructure packing, strength and durability of non-shaped composite building materials such as concrete and mortar. A comparative study of performances of rendering mortars with different quantities of micro silica was conducted. The experimental program included production of reference mortar based on Portland cement and quartz sand (CM) and three mortars with 5, 10, and 15 % addition of micro silica (SCM-5, SCM-10, and SCM-15). The effect that micro silica addition has on the thermal behavior and mechanical properties of mortars was discussed. Hydration mechanisms and thermally induced reactions were studied at temperatures ranging from ambient to 1100 degrees C by differential thermal analysis. The results were supported by X-ray diffraction analysis. The cementing efficiency of micro silica was assessed by cavitation erosion test. The changes in the morphology of mortar samples prior and upon cavitation testing were monitored by means of the scanning electron microscope imagining. It was found that 5 % of superfine micro silica (SCM-5 mortar) has positive effects on mechanical strengths (15 % increase in compressive strength) due to microstructure densification arising from the successive filling of voids by the micro silica. Addition of micro silica also improved the cavitation erosion resistance in comparison with reference cement mortar (SCM-5 showed cavitation velocity as low as 0.09 mg/min). This qualifies mortars with micro silica addition as building materials which can be safely employed in potential hydro-demolition environment.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Cavitation Properties of Rendering Mortars with Micro Silica Addition
EP  - 459
IS  - 4
SP  - 445
VL  - 53
DO  - 10.2298/SOS2104445T
ER  - 

@article{
author = "Terzić, Anja and Dojčinović, Marina and Miličić, Ljiljana and Stojanović, Jovica and Radojević, Zagorka",
year = "2021",
abstract = "Micro-silica is a highly efficient mineral additive whose role is reflected in improvements of microstructure packing, strength and durability of non-shaped composite building materials such as concrete and mortar. A comparative study of performances of rendering mortars with different quantities of micro silica was conducted. The experimental program included production of reference mortar based on Portland cement and quartz sand (CM) and three mortars with 5, 10, and 15 % addition of micro silica (SCM-5, SCM-10, and SCM-15). The effect that micro silica addition has on the thermal behavior and mechanical properties of mortars was discussed. Hydration mechanisms and thermally induced reactions were studied at temperatures ranging from ambient to 1100 degrees C by differential thermal analysis. The results were supported by X-ray diffraction analysis. The cementing efficiency of micro silica was assessed by cavitation erosion test. The changes in the morphology of mortar samples prior and upon cavitation testing were monitored by means of the scanning electron microscope imagining. It was found that 5 % of superfine micro silica (SCM-5 mortar) has positive effects on mechanical strengths (15 % increase in compressive strength) due to microstructure densification arising from the successive filling of voids by the micro silica. Addition of micro silica also improved the cavitation erosion resistance in comparison with reference cement mortar (SCM-5 showed cavitation velocity as low as 0.09 mg/min). This qualifies mortars with micro silica addition as building materials which can be safely employed in potential hydro-demolition environment.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Cavitation Properties of Rendering Mortars with Micro Silica Addition",
pages = "459-445",
number = "4",
volume = "53",
doi = "10.2298/SOS2104445T"
}

Terzić, A., Dojčinović, M., Miličić, L., Stojanović, J.,& Radojević, Z.. (2021). Cavitation Properties of Rendering Mortars with Micro Silica Addition. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 53(4), 445-459.
https://doi.org/10.2298/SOS2104445T

Terzić A, Dojčinović M, Miličić L, Stojanović J, Radojević Z. Cavitation Properties of Rendering Mortars with Micro Silica Addition. in Science of Sintering. 2021;53(4):445-459.
doi:10.2298/SOS2104445T .

Terzić, Anja, Dojčinović, Marina, Miličić, Ljiljana, Stojanović, Jovica, Radojević, Zagorka, "Cavitation Properties of Rendering Mortars with Micro Silica Addition" in Science of Sintering, 53, no. 4 (2021):445-459,
https://doi.org/10.2298/SOS2104445T . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Radulović, Dragan
AU  - Pezo, Milada
AU  - Stojanović, Jovica
AU  - Pezo, Lato
AU  - Radojević, Zagorka
AU  - Andrić, Ljubiša
PY  - 2020
UR  - http://rims.institutims.rs/handle/123456789/393
AB  - The optimal outputs of pyrophyllite mechano-chemical activation in an ultra-centrifugal mill performing under different technological conditions were determined by analytical modeling and verified via Artificial Neural Network in order to be employed in the production of cement-based binders. Cluster Analysis and Principal Component Analysis were utilized in assessment of the effect of activation process parameters on the activated pyrophyllite quality. Artificial Neural Network which performed with high prediction accuracy, i.e. 0.914 during the training period, was sufficient for precise prediction of activated pyrophyllite quality in a wide range of processing parameters. The probability of utilization of observed activation products was estimated through interrelation of technological parameters (mesh size sieve, activation period, specific energy consumption) and acquired characteristics of pyrophyllite (grain diameter, specific surface area). The optimal products singled out from each activation sequence were used as mineral additives in the mix-designs of four cement binders (cement replacement portion was 30%). Influence of activated pyrophyllite additions on the cement chemistry, mineral phase compositions and microstructures of the cement binders were monitored by instrumental techniques (DTA/TGA, XRD, SEM). Activated pyrophyllite showed characteristics of pozzolana as it slightly accelerated early stages of hydration, decreased cement hydration energy and increased the quantity of cement mineral alite at later hydration stages. Micron-sized crystalline foila characteristic for mechanically activated pyrophyllite formed micro-reinforcement within cement binder microstructure.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - Prediction model based on artificial neural network for pyrophyllite mechano-chemical activation as an integral step in production of cement binders
VL  - 258
DO  - 10.1016/j.conbuildmat.2020.119721
ER  - 

@article{
author = "Terzić, Anja and Radulović, Dragan and Pezo, Milada and Stojanović, Jovica and Pezo, Lato and Radojević, Zagorka and Andrić, Ljubiša",
year = "2020",
abstract = "The optimal outputs of pyrophyllite mechano-chemical activation in an ultra-centrifugal mill performing under different technological conditions were determined by analytical modeling and verified via Artificial Neural Network in order to be employed in the production of cement-based binders. Cluster Analysis and Principal Component Analysis were utilized in assessment of the effect of activation process parameters on the activated pyrophyllite quality. Artificial Neural Network which performed with high prediction accuracy, i.e. 0.914 during the training period, was sufficient for precise prediction of activated pyrophyllite quality in a wide range of processing parameters. The probability of utilization of observed activation products was estimated through interrelation of technological parameters (mesh size sieve, activation period, specific energy consumption) and acquired characteristics of pyrophyllite (grain diameter, specific surface area). The optimal products singled out from each activation sequence were used as mineral additives in the mix-designs of four cement binders (cement replacement portion was 30%). Influence of activated pyrophyllite additions on the cement chemistry, mineral phase compositions and microstructures of the cement binders were monitored by instrumental techniques (DTA/TGA, XRD, SEM). Activated pyrophyllite showed characteristics of pozzolana as it slightly accelerated early stages of hydration, decreased cement hydration energy and increased the quantity of cement mineral alite at later hydration stages. Micron-sized crystalline foila characteristic for mechanically activated pyrophyllite formed micro-reinforcement within cement binder microstructure.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "Prediction model based on artificial neural network for pyrophyllite mechano-chemical activation as an integral step in production of cement binders",
volume = "258",
doi = "10.1016/j.conbuildmat.2020.119721"
}

Terzić, A., Radulović, D., Pezo, M., Stojanović, J., Pezo, L., Radojević, Z.,& Andrić, L.. (2020). Prediction model based on artificial neural network for pyrophyllite mechano-chemical activation as an integral step in production of cement binders. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 258.
https://doi.org/10.1016/j.conbuildmat.2020.119721

Terzić A, Radulović D, Pezo M, Stojanović J, Pezo L, Radojević Z, Andrić L. Prediction model based on artificial neural network for pyrophyllite mechano-chemical activation as an integral step in production of cement binders. in Construction and Building Materials. 2020;258.
doi:10.1016/j.conbuildmat.2020.119721 .

Terzić, Anja, Radulović, Dragan, Pezo, Milada, Stojanović, Jovica, Pezo, Lato, Radojević, Zagorka, Andrić, Ljubiša, "Prediction model based on artificial neural network for pyrophyllite mechano-chemical activation as an integral step in production of cement binders" in Construction and Building Materials, 258 (2020),
https://doi.org/10.1016/j.conbuildmat.2020.119721 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Stojanović, Jovica
AU  - Andrić, Ljubiša
AU  - Miličić, Ljiljana
AU  - Radojević, Zagorka
PY  - 2020
UR  - http://rims.institutims.rs/handle/123456789/390
AB  - This experimental study was conducted with an aim to investigate the effect of the elevated temperature on the mineral phase composition, microstructure and mechanical properties of the thermal insulation lightweight concretes. The first group of experimental concretes was based on the expanded vermiculite and expanded perlite used as lightweight aggregates (in 65 wt%) in combination with either ordinary Portland cement or refractory calcium aluminate cement. The mix-design of the second group of concretes comprised standard quartz aggregate, vermiculite or perlite as aggregate replacement (25 wt%) and binder (PC or CAC). A total of 10 concrete mix-designs were fabricated in form of 40x40x160 mm samples which were submitted to heat-treatment at 400 degrees, 600 degrees, 800 degrees and 1000 degrees C upon standard 28-days period of curing and hardening. The changes in crystallinity and mineral phase composition induced by temperature were monitored by X-ray diffraction technique. Microstructural visualizations of the non-fired and fired concrete samples were conducted by scanning electron microscopy accompanied with EDX analysis. The results indicated that despite the decrease in compressive strengths upon firing, investigated lightweight concretes can be categorized both as thermal insulators and structural materials.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes
EP  - 162
IS  - 2
SP  - 149
VL  - 52
DO  - 10.2298/SOS2002149T
ER  - 

@article{
author = "Terzić, Anja and Stojanović, Jovica and Andrić, Ljubiša and Miličić, Ljiljana and Radojević, Zagorka",
year = "2020",
abstract = "This experimental study was conducted with an aim to investigate the effect of the elevated temperature on the mineral phase composition, microstructure and mechanical properties of the thermal insulation lightweight concretes. The first group of experimental concretes was based on the expanded vermiculite and expanded perlite used as lightweight aggregates (in 65 wt%) in combination with either ordinary Portland cement or refractory calcium aluminate cement. The mix-design of the second group of concretes comprised standard quartz aggregate, vermiculite or perlite as aggregate replacement (25 wt%) and binder (PC or CAC). A total of 10 concrete mix-designs were fabricated in form of 40x40x160 mm samples which were submitted to heat-treatment at 400 degrees, 600 degrees, 800 degrees and 1000 degrees C upon standard 28-days period of curing and hardening. The changes in crystallinity and mineral phase composition induced by temperature were monitored by X-ray diffraction technique. Microstructural visualizations of the non-fired and fired concrete samples were conducted by scanning electron microscopy accompanied with EDX analysis. The results indicated that despite the decrease in compressive strengths upon firing, investigated lightweight concretes can be categorized both as thermal insulators and structural materials.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes",
pages = "162-149",
number = "2",
volume = "52",
doi = "10.2298/SOS2002149T"
}

Terzić, A., Stojanović, J., Andrić, L., Miličić, L.,& Radojević, Z.. (2020). Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 52(2), 149-162.
https://doi.org/10.2298/SOS2002149T

Terzić A, Stojanović J, Andrić L, Miličić L, Radojević Z. Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes. in Science of Sintering. 2020;52(2):149-162.
doi:10.2298/SOS2002149T .

Terzić, Anja, Stojanović, Jovica, Andrić, Ljubiša, Miličić, Ljiljana, Radojević, Zagorka, "Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes" in Science of Sintering, 52, no. 2 (2020):149-162,
https://doi.org/10.2298/SOS2002149T . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Stojanović, Jovica
AU  - Đorđević, Antonije
AU  - Andrić, Ljubiša
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://rims.institutims.rs/handle/123456789/373
AB  - Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources - talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 degrees C and holding period conducted at 1250 degrees C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics
EP  - 3022
IS  - 3
SP  - 3013
VL  - 45
DO  - 10.1016/j.ceramint.2018.10.120
ER  - 

@article{
author = "Terzić, Anja and Obradović, Nina and Kosanović, Darko and Stojanović, Jovica and Đorđević, Antonije and Andrić, Ljubiša and Pavlović, Vladimir",
year = "2019",
abstract = "Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources - talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 degrees C and holding period conducted at 1250 degrees C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics",
pages = "3022-3013",
number = "3",
volume = "45",
doi = "10.1016/j.ceramint.2018.10.120"
}

Terzić, A., Obradović, N., Kosanović, D., Stojanović, J., Đorđević, A., Andrić, L.,& Pavlović, V.. (2019). Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International
Elsevier Sci Ltd, Oxford., 45(3), 3013-3022.
https://doi.org/10.1016/j.ceramint.2018.10.120

Terzić A, Obradović N, Kosanović D, Stojanović J, Đorđević A, Andrić L, Pavlović V. Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International. 2019;45(3):3013-3022.
doi:10.1016/j.ceramint.2018.10.120 .

Terzić, Anja, Obradović, Nina, Kosanović, Darko, Stojanović, Jovica, Đorđević, Antonije, Andrić, Ljubiša, Pavlović, Vladimir, "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics" in Ceramics International, 45, no. 3 (2019):3013-3022,
https://doi.org/10.1016/j.ceramint.2018.10.120 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Mijatović, Nevenka
AU  - Stojanović, Jovica
AU  - Kragović, Milan
AU  - Miličić, Ljiljana
AU  - Andrić, Ljubiša
PY  - 2018
UR  - http://rims.institutims.rs/handle/123456789/345
AB  - Instrumental analyses accompanied by analytical modeling tools were employed to assess physico-chemical changes induced by variations in chemical composition of cementitious composites, i.e. mortar binders. Coal combustion ash was utilized as pozzolanic mineral additive. The binders' mix-design was supplemented with sorptive clays to prevent migration of toxic elements from fly ash. The experiment was established on the premise of clay's ion-exchanging ability. Ten binders comprising cement CEM I 42.5 and fly ash, zeolite and/or bentonite additions were prepared in accordance with chemometric experimental design rules. Chemical composition was determined via XRF method. The changes in mineral phases and crystallinity were traced by X-ray diffraction. Hydration mechanisms and thermal behavior were investigated via DTA/TGA. The chemical bonds were identified by FTIR. Morphology of hardened samples was detected by SEM. Mathematical tools employed data sets of instrumental analyses to form a clear differentiation between binders and to assess changes caused by adoption of mineral additives in the mix designs. Sorptive clays showed pozzolanic behavior, thereby causing no incapacitation to the cement hydration mechanism, and classifying as a possible economical resources which can be used in production technology of construction materials to redeem environmental pollution issues of building industry.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders
EP  - 210
SP  - 199
VL  - 180
DO  - 10.1016/j.conbuildmat.2018.06.007
ER  - 

@article{
author = "Terzić, Anja and Pezo, Lato and Mijatović, Nevenka and Stojanović, Jovica and Kragović, Milan and Miličić, Ljiljana and Andrić, Ljubiša",
year = "2018",
abstract = "Instrumental analyses accompanied by analytical modeling tools were employed to assess physico-chemical changes induced by variations in chemical composition of cementitious composites, i.e. mortar binders. Coal combustion ash was utilized as pozzolanic mineral additive. The binders' mix-design was supplemented with sorptive clays to prevent migration of toxic elements from fly ash. The experiment was established on the premise of clay's ion-exchanging ability. Ten binders comprising cement CEM I 42.5 and fly ash, zeolite and/or bentonite additions were prepared in accordance with chemometric experimental design rules. Chemical composition was determined via XRF method. The changes in mineral phases and crystallinity were traced by X-ray diffraction. Hydration mechanisms and thermal behavior were investigated via DTA/TGA. The chemical bonds were identified by FTIR. Morphology of hardened samples was detected by SEM. Mathematical tools employed data sets of instrumental analyses to form a clear differentiation between binders and to assess changes caused by adoption of mineral additives in the mix designs. Sorptive clays showed pozzolanic behavior, thereby causing no incapacitation to the cement hydration mechanism, and classifying as a possible economical resources which can be used in production technology of construction materials to redeem environmental pollution issues of building industry.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders",
pages = "210-199",
volume = "180",
doi = "10.1016/j.conbuildmat.2018.06.007"
}

Terzić, A., Pezo, L., Mijatović, N., Stojanović, J., Kragović, M., Miličić, L.,& Andrić, L.. (2018). The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 180, 199-210.
https://doi.org/10.1016/j.conbuildmat.2018.06.007

Terzić A, Pezo L, Mijatović N, Stojanović J, Kragović M, Miličić L, Andrić L. The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders. in Construction and Building Materials. 2018;180:199-210.
doi:10.1016/j.conbuildmat.2018.06.007 .

Terzić, Anja, Pezo, Lato, Mijatović, Nevenka, Stojanović, Jovica, Kragović, Milan, Miličić, Ljiljana, Andrić, Ljubiša, "The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders" in Construction and Building Materials, 180 (2018):199-210,
https://doi.org/10.1016/j.conbuildmat.2018.06.007 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Pouchly, Vaclav
AU  - Stojanović, Jovica
AU  - Maca, Karel
AU  - Pavlović, Vladimir
PY  - 2018
UR  - http://rims.institutims.rs/handle/123456789/340
AB  - The influence of the sintering method on the mineral phase transformations and development of the crystalline microstructure of steatite ceramics was investigated. The steatite samples were fabricated from talc and bentonite as low-cost raw materials. Feldspar and barium carbonate, as fluxing agents, were altered in the steatite composition. Dilatometric analysis was applied in the monitoring of the dimensional changes and thereby densification of steatite during the traditional sintering (TS) procedure up to 1200 degrees C. Spark plasma sintering (SPS) method was used under the following sintering conditions: 100 degrees C/min heating rate, uniaxial pressure of 50 MPa; sintering temperature 800 degrees C/1 min or 1000 degrees C/2 min. Crystallinity changes and mineral phase transition during sintering were observed by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy equipped with the EDS mapping. It was found that SPS sintering facilitated all microstructural changes during high temperature treatment and shifted them to lower temperatures. SPS treatment conducted at 1000 degrees C resulted in maximum densification of the steatite powder compacts and the formation stabilized protoenstatite structure.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering
EP  - 312
IS  - 3
SP  - 299
VL  - 50
DO  - 10.2298/SOS1803299T
ER  - 

@article{
author = "Terzić, Anja and Obradović, Nina and Pouchly, Vaclav and Stojanović, Jovica and Maca, Karel and Pavlović, Vladimir",
year = "2018",
abstract = "The influence of the sintering method on the mineral phase transformations and development of the crystalline microstructure of steatite ceramics was investigated. The steatite samples were fabricated from talc and bentonite as low-cost raw materials. Feldspar and barium carbonate, as fluxing agents, were altered in the steatite composition. Dilatometric analysis was applied in the monitoring of the dimensional changes and thereby densification of steatite during the traditional sintering (TS) procedure up to 1200 degrees C. Spark plasma sintering (SPS) method was used under the following sintering conditions: 100 degrees C/min heating rate, uniaxial pressure of 50 MPa; sintering temperature 800 degrees C/1 min or 1000 degrees C/2 min. Crystallinity changes and mineral phase transition during sintering were observed by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy equipped with the EDS mapping. It was found that SPS sintering facilitated all microstructural changes during high temperature treatment and shifted them to lower temperatures. SPS treatment conducted at 1000 degrees C resulted in maximum densification of the steatite powder compacts and the formation stabilized protoenstatite structure.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering",
pages = "312-299",
number = "3",
volume = "50",
doi = "10.2298/SOS1803299T"
}

Terzić, A., Obradović, N., Pouchly, V., Stojanović, J., Maca, K.,& Pavlović, V.. (2018). Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(3), 299-312.
https://doi.org/10.2298/SOS1803299T

Terzić A, Obradović N, Pouchly V, Stojanović J, Maca K, Pavlović V. Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering. in Science of Sintering. 2018;50(3):299-312.
doi:10.2298/SOS1803299T .

Terzić, Anja, Obradović, Nina, Pouchly, Vaclav, Stojanović, Jovica, Maca, Karel, Pavlović, Vladimir, "Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering" in Science of Sintering, 50, no. 3 (2018):299-312,
https://doi.org/10.2298/SOS1803299T . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Radulović, Dragan
AU  - Pezo, Lato
AU  - Andrić, Ljubiša
AU  - Miličić, Ljiljana
AU  - Stojanović, Jovica
AU  - Grigorova, Irena
PY  - 2017
UR  - http://rims.institutims.rs/handle/123456789/322
AB  - The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.
PB  - Elsevier Sci Ltd, Oxford
T2  - Composites Part B-Engineering
T1  - The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites
EP  - 73
SP  - 61
VL  - 117
DO  - 10.1016/j.compositesb.2017.02.041
ER  - 

@article{
author = "Terzić, Anja and Radulović, Dragan and Pezo, Lato and Andrić, Ljubiša and Miličić, Ljiljana and Stojanović, Jovica and Grigorova, Irena",
year = "2017",
abstract = "The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Composites Part B-Engineering",
title = "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites",
pages = "73-61",
volume = "117",
doi = "10.1016/j.compositesb.2017.02.041"
}

Terzić, A., Radulović, D., Pezo, L., Andrić, L., Miličić, L., Stojanović, J.,& Grigorova, I.. (2017). The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering
Elsevier Sci Ltd, Oxford., 117, 61-73.
https://doi.org/10.1016/j.compositesb.2017.02.041

Terzić A, Radulović D, Pezo L, Andrić L, Miličić L, Stojanović J, Grigorova I. The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering. 2017;117:61-73.
doi:10.1016/j.compositesb.2017.02.041 .

Terzić, Anja, Radulović, Dragan, Pezo, Lato, Andrić, Ljubiša, Miličić, Ljiljana, Stojanović, Jovica, Grigorova, Irena, "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites" in Composites Part B-Engineering, 117 (2017):61-73,
https://doi.org/10.1016/j.compositesb.2017.02.041 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Stojanović, Jovica
AU  - Pavlović, Vladimir
AU  - Andrić, Ljubiša
AU  - Olcan, Dragan
AU  - Đorđević, Antonije
PY  - 2017
UR  - http://rims.institutims.rs/handle/123456789/314
AB  - The focus of the study was on providing insights into interconnections between sintering and development of the crystalline microstructure, and consequently variations in dielectric behavior of four steatites fabricated from a low-cost raw material, i.e. talc. The changes, induced by the alternations of the binders (bentonite, kaolin clay) and fluxing agents (BaCO3, feldspar), were monitored in the temperature range 1000 degrees to 1250 degrees C in which complete densification and re-crystallization of the investigated structures were accomplished. The critical points in the synthesis of steatite materials were assessed by instrumental analyses. Crystallinity changes and mineral phase transition during sintering were monitored by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy accompanied with EDS mapping. The thermal stability was observed on the green mixtures using differential thermal and thermo gravimetric analyses. Electrical measurements recorded variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the sintering temperature. The investigation highlighted critical design points, as well as the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials
EP  - 13275
IS  - 16
SP  - 13264
VL  - 43
DO  - 10.1016/j.ceramint.2017.07.024
ER  - 

@article{
author = "Terzić, Anja and Obradović, Nina and Stojanović, Jovica and Pavlović, Vladimir and Andrić, Ljubiša and Olcan, Dragan and Đorđević, Antonije",
year = "2017",
abstract = "The focus of the study was on providing insights into interconnections between sintering and development of the crystalline microstructure, and consequently variations in dielectric behavior of four steatites fabricated from a low-cost raw material, i.e. talc. The changes, induced by the alternations of the binders (bentonite, kaolin clay) and fluxing agents (BaCO3, feldspar), were monitored in the temperature range 1000 degrees to 1250 degrees C in which complete densification and re-crystallization of the investigated structures were accomplished. The critical points in the synthesis of steatite materials were assessed by instrumental analyses. Crystallinity changes and mineral phase transition during sintering were monitored by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy accompanied with EDS mapping. The thermal stability was observed on the green mixtures using differential thermal and thermo gravimetric analyses. Electrical measurements recorded variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the sintering temperature. The investigation highlighted critical design points, as well as the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials",
pages = "13275-13264",
number = "16",
volume = "43",
doi = "10.1016/j.ceramint.2017.07.024"
}

Terzić, A., Obradović, N., Stojanović, J., Pavlović, V., Andrić, L., Olcan, D.,& Đorđević, A.. (2017). Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(16), 13264-13275.
https://doi.org/10.1016/j.ceramint.2017.07.024

Terzić A, Obradović N, Stojanović J, Pavlović V, Andrić L, Olcan D, Đorđević A. Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials. in Ceramics International. 2017;43(16):13264-13275.
doi:10.1016/j.ceramint.2017.07.024 .

Terzić, Anja, Obradović, Nina, Stojanović, Jovica, Pavlović, Vladimir, Andrić, Ljubiša, Olcan, Dragan, Đorđević, Antonije, "Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials" in Ceramics International, 43, no. 16 (2017):13264-13275,
https://doi.org/10.1016/j.ceramint.2017.07.024 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Andrić, Ljubiša
AU  - Stojanović, Jovica
AU  - Pavlović, Vladimir
PY  - 2015
UR  - http://rims.institutims.rs/handle/123456789/266
AB  - The effects that the fly ash addition has on the behavior of thermally resistant corundum concrete were discussed. Experimental program implied production of two refractory composites: "referent" concrete from 20 % of high-aluminate cement and 80 % of corundum aggregate, "recycled" concrete from 10 % of high-aluminate cement, 20 % of lignite coal ash, and 70 % of corundum aggregate. The fly ash was mechanically activated by a vibratory disk mill. In the concrete matrix, the ash had a role of cement partial replacement and microfiller. The mechanical and thermal properties of the concretes were studied at temperatures ranging from ambient to 1,400 A degrees C as adopted maximum. Mechanisms of thermally induced processes were observed by differential thermal analysis at 10, 20, and 30 A degrees C min(-1) heating rates. Referent and recycled concretes showed differences in calculated activation energies. The variations in refractory concretes performances were discussed with support of scanning electron microscope imagining and X-ray diffraction results. The recycled ash concrete exhibited properties that met the requirements for the castables, which proves it suitable for use in severe conditions at high temperature and highlights the reusing principle and possibility of cleaner and economically sustainable production.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash
EP  - 1352
IS  - 2
SP  - 1339
VL  - 119
DO  - 10.1007/s10973-014-4230-4
ER  - 

@article{
author = "Terzić, Anja and Obradović, Nina and Andrić, Ljubiša and Stojanović, Jovica and Pavlović, Vladimir",
year = "2015",
abstract = "The effects that the fly ash addition has on the behavior of thermally resistant corundum concrete were discussed. Experimental program implied production of two refractory composites: "referent" concrete from 20 % of high-aluminate cement and 80 % of corundum aggregate, "recycled" concrete from 10 % of high-aluminate cement, 20 % of lignite coal ash, and 70 % of corundum aggregate. The fly ash was mechanically activated by a vibratory disk mill. In the concrete matrix, the ash had a role of cement partial replacement and microfiller. The mechanical and thermal properties of the concretes were studied at temperatures ranging from ambient to 1,400 A degrees C as adopted maximum. Mechanisms of thermally induced processes were observed by differential thermal analysis at 10, 20, and 30 A degrees C min(-1) heating rates. Referent and recycled concretes showed differences in calculated activation energies. The variations in refractory concretes performances were discussed with support of scanning electron microscope imagining and X-ray diffraction results. The recycled ash concrete exhibited properties that met the requirements for the castables, which proves it suitable for use in severe conditions at high temperature and highlights the reusing principle and possibility of cleaner and economically sustainable production.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash",
pages = "1352-1339",
number = "2",
volume = "119",
doi = "10.1007/s10973-014-4230-4"
}

Terzić, A., Obradović, N., Andrić, L., Stojanović, J.,& Pavlović, V.. (2015). Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 119(2), 1339-1352.
https://doi.org/10.1007/s10973-014-4230-4

Terzić A, Obradović N, Andrić L, Stojanović J, Pavlović V. Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash. in Journal of Thermal Analysis and Calorimetry. 2015;119(2):1339-1352.
doi:10.1007/s10973-014-4230-4 .

Terzić, Anja, Obradović, Nina, Andrić, Ljubiša, Stojanović, Jovica, Pavlović, Vladimir, "Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash" in Journal of Thermal Analysis and Calorimetry, 119, no. 2 (2015):1339-1352,
https://doi.org/10.1007/s10973-014-4230-4 . .

TY  - JOUR
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Petrov, Milan
AU  - Stojanović, Jovica
AU  - Kostović, Milena
PY  - 2015
UR  - http://rims.institutims.rs/handle/123456789/272
AB  - The aim of this investigation was to establish the optimal processing parameters of the comminuted phosphate grain mixture mechanical treatment by monitoring and evaluating the activated product characteristics. An ultra-centrifugal mill with a peripheral comminuting path was used as activator in the experiment. A mathematical model based on the theoretical principles of the grain mixture mechanical processing was applied in order to characterize the phosphate activation procedure. As the energy conversion that takes place by the interaction mill-material during activation is recorded on the processed phosphate grains, the increase in potential energy of the activated grains was measured by means of an automatic grain counter. Following the operating hypothesis of the automatic grain counter, the energy conversion and the properties of phosphate grains induced by mechanical force were monitored and expressed in the form of the grain inertia change. The phosphate ore grain mixture used in the experiment was thoroughly analyzed, particularly in its activated state. Analytically obtained results were supported by X-ray diffraction analysis for identification of crystalline phases and change in crystallinity, and SEM microphotography of initial and activated phosphate grains. Diverse comparison analyses disclosed that the optimal set of activation process parameters could reduce the negative effect of phosphate sample immanent properties on the final score and furthermore enhance the material reactivity.
PB  - Elsevier, Amsterdam
T2  - International Journal of Mineral Processing
T1  - Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill
EP  - 11
SP  - 1
VL  - 143
DO  - 10.1016/j.minpro.2015.08.005
ER  - 

@article{
author = "Andrić, Ljubiša and Terzić, Anja and Petrov, Milan and Stojanović, Jovica and Kostović, Milena",
year = "2015",
abstract = "The aim of this investigation was to establish the optimal processing parameters of the comminuted phosphate grain mixture mechanical treatment by monitoring and evaluating the activated product characteristics. An ultra-centrifugal mill with a peripheral comminuting path was used as activator in the experiment. A mathematical model based on the theoretical principles of the grain mixture mechanical processing was applied in order to characterize the phosphate activation procedure. As the energy conversion that takes place by the interaction mill-material during activation is recorded on the processed phosphate grains, the increase in potential energy of the activated grains was measured by means of an automatic grain counter. Following the operating hypothesis of the automatic grain counter, the energy conversion and the properties of phosphate grains induced by mechanical force were monitored and expressed in the form of the grain inertia change. The phosphate ore grain mixture used in the experiment was thoroughly analyzed, particularly in its activated state. Analytically obtained results were supported by X-ray diffraction analysis for identification of crystalline phases and change in crystallinity, and SEM microphotography of initial and activated phosphate grains. Diverse comparison analyses disclosed that the optimal set of activation process parameters could reduce the negative effect of phosphate sample immanent properties on the final score and furthermore enhance the material reactivity.",
publisher = "Elsevier, Amsterdam",
journal = "International Journal of Mineral Processing",
title = "Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill",
pages = "11-1",
volume = "143",
doi = "10.1016/j.minpro.2015.08.005"
}

Andrić, L., Terzić, A., Petrov, M., Stojanović, J.,& Kostović, M.. (2015). Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill. in International Journal of Mineral Processing
Elsevier, Amsterdam., 143, 1-11.
https://doi.org/10.1016/j.minpro.2015.08.005

Andrić L, Terzić A, Petrov M, Stojanović J, Kostović M. Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill. in International Journal of Mineral Processing. 2015;143:1-11.
doi:10.1016/j.minpro.2015.08.005 .

Andrić, Ljubiša, Terzić, Anja, Petrov, Milan, Stojanović, Jovica, Kostović, Milena, "Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill" in International Journal of Mineral Processing, 143 (2015):1-11,
https://doi.org/10.1016/j.minpro.2015.08.005 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
AU  - Stojanović, Jovica
AU  - Obradović, Nina
AU  - Kostović, Milena
PY  - 2014
UR  - http://rims.institutims.rs/handle/123456789/236
AB  - The effect of vibratory mill induced mechanical activation on the change of the particle size, crystallinity and the phase transformations of the minerals present in the activated material, was studied with the purpose of decreasing of the sintering temperature of talc (Mg3Si4O10(OH)(2)) as raw material which is the basic component of the steatite ceramics. The aims of the conducted investigation were, also, increasing of the reactivity of the comminuted raw material and establishing of the optimal activation period. The properties of the activated talc induced by mechanical force were expressed in form of the grain inertia change which was measured by means of automatic grain counter. Mechanically activated grains are the most convenient mineral form for physical concentration since the energy change of the mill-material system is recorded on them. The effect of dry grinding on the structure, particle size and shape of talc was studied by means of XRD, DTA and SEM/EDS methods. Activation of talc produced an increase of the starting surface area value progressively from 4.5 m(2)/g up to a maximum of 108.5 m(2)/g achieved at 30 min. A subsequent decrease of rate of surface area change and the rate of size reduction were observed following the prolonged grinding. Talc activated in vibratory mill for optimal 30 min showed properties which positively influence the decrease of sintering temperature and the increase of the sintering rate of steatite ceramics.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics
EP  - 258
IS  - 2
SP  - 247
VL  - 46
DO  - 10.2298/SOS1402247T
ER  - 

@article{
author = "Terzić, Anja and Andrić, Ljubiša and Stojanović, Jovica and Obradović, Nina and Kostović, Milena",
year = "2014",
abstract = "The effect of vibratory mill induced mechanical activation on the change of the particle size, crystallinity and the phase transformations of the minerals present in the activated material, was studied with the purpose of decreasing of the sintering temperature of talc (Mg3Si4O10(OH)(2)) as raw material which is the basic component of the steatite ceramics. The aims of the conducted investigation were, also, increasing of the reactivity of the comminuted raw material and establishing of the optimal activation period. The properties of the activated talc induced by mechanical force were expressed in form of the grain inertia change which was measured by means of automatic grain counter. Mechanically activated grains are the most convenient mineral form for physical concentration since the energy change of the mill-material system is recorded on them. The effect of dry grinding on the structure, particle size and shape of talc was studied by means of XRD, DTA and SEM/EDS methods. Activation of talc produced an increase of the starting surface area value progressively from 4.5 m(2)/g up to a maximum of 108.5 m(2)/g achieved at 30 min. A subsequent decrease of rate of surface area change and the rate of size reduction were observed following the prolonged grinding. Talc activated in vibratory mill for optimal 30 min showed properties which positively influence the decrease of sintering temperature and the increase of the sintering rate of steatite ceramics.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics",
pages = "258-247",
number = "2",
volume = "46",
doi = "10.2298/SOS1402247T"
}

Terzić, A., Andrić, L., Stojanović, J., Obradović, N.,& Kostović, M.. (2014). Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 46(2), 247-258.
https://doi.org/10.2298/SOS1402247T

Terzić A, Andrić L, Stojanović J, Obradović N, Kostović M. Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics. in Science of Sintering. 2014;46(2):247-258.
doi:10.2298/SOS1402247T .

Terzić, Anja, Andrić, Ljubiša, Stojanović, Jovica, Obradović, Nina, Kostović, Milena, "Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics" in Science of Sintering, 46, no. 2 (2014):247-258,
https://doi.org/10.2298/SOS1402247T . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Radojević, Zagorka
AU  - Miličić, Ljiljana
AU  - Pavlović, Ljubica
AU  - Stojanović, Jovica
PY  - 2013
UR  - http://rims.institutims.rs/handle/123456789/203
AB  - High-temperature concrete binders in which fly ash, as environmentally harmful secondary raw material, is combined with masonry and refractory cement is a new option for reapplication of this coal combustion by-product. In this study, the design of the bonding agents was based on the fly ash from lignite coal combustion process and two types of cement: Portland cement and aluminate cement. Fly ash was applied without any further mechanical or thermal treatment. Mechanical properties of the binders were investigated and subsequently correlated with changes which occurred in the phase composition and microstructure of the agents. Scanning electron microscopy was used in investigation of microstructural changes caused by temperature. X-ray diffraction method was used in monitoring of the mineral phase changes also induced by increasing temperature. The investigations conducted on the bonding agents highlighted presence of good refractory properties and temperature-resistance, and also showed high values of compressive strength. The investigated bonding agents, thus, can be applied in refractory concretes, but also in various types of thermo-insulations.
T2  - Revista Romana de Materiale/ Romanian Journal of Materials
T1  - High-temperature concrete binders based on fly ash
EP  - 275
IS  - 3
SP  - 269
VL  - 43
UR  - https://hdl.handle.net/21.15107/rcub_rims_203
ER  - 

@article{
author = "Terzić, Anja and Radojević, Zagorka and Miličić, Ljiljana and Pavlović, Ljubica and Stojanović, Jovica",
year = "2013",
abstract = "High-temperature concrete binders in which fly ash, as environmentally harmful secondary raw material, is combined with masonry and refractory cement is a new option for reapplication of this coal combustion by-product. In this study, the design of the bonding agents was based on the fly ash from lignite coal combustion process and two types of cement: Portland cement and aluminate cement. Fly ash was applied without any further mechanical or thermal treatment. Mechanical properties of the binders were investigated and subsequently correlated with changes which occurred in the phase composition and microstructure of the agents. Scanning electron microscopy was used in investigation of microstructural changes caused by temperature. X-ray diffraction method was used in monitoring of the mineral phase changes also induced by increasing temperature. The investigations conducted on the bonding agents highlighted presence of good refractory properties and temperature-resistance, and also showed high values of compressive strength. The investigated bonding agents, thus, can be applied in refractory concretes, but also in various types of thermo-insulations.",
journal = "Revista Romana de Materiale/ Romanian Journal of Materials",
title = "High-temperature concrete binders based on fly ash",
pages = "275-269",
number = "3",
volume = "43",
url = "https://hdl.handle.net/21.15107/rcub_rims_203"
}

Terzić, A., Radojević, Z., Miličić, L., Pavlović, L.,& Stojanović, J.. (2013). High-temperature concrete binders based on fly ash. in Revista Romana de Materiale/ Romanian Journal of Materials, 43(3), 269-275.
https://hdl.handle.net/21.15107/rcub_rims_203

Terzić A, Radojević Z, Miličić L, Pavlović L, Stojanović J. High-temperature concrete binders based on fly ash. in Revista Romana de Materiale/ Romanian Journal of Materials. 2013;43(3):269-275.
https://hdl.handle.net/21.15107/rcub_rims_203 .

Terzić, Anja, Radojević, Zagorka, Miličić, Ljiljana, Pavlović, Ljubica, Stojanović, Jovica, "High-temperature concrete binders based on fly ash" in Revista Romana de Materiale/ Romanian Journal of Materials, 43, no. 3 (2013):269-275,
https://hdl.handle.net/21.15107/rcub_rims_203 .

TY  - JOUR
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
AU  - Obradović, Nina
AU  - Pavlović, Vladimir
AU  - Stojanović, Jovica
AU  - Miličić, Ljiljana
AU  - Radojević, Zagorka
AU  - Ristić, M.M.
PY  - 2012
UR  - http://rims.institutims.rs/handle/123456789/155
AB  - Količina letećeg pepela koji se proizvodi i koja će biti proizvedena u godinama koje dolaze zahteva razvoj novih metoda recikliranja u kojima će biti upotrebljene značajne količine ovog otpadnog materijala. Mogućnost visoko-temperaturne aplikacije (termoizolacioni i vatrostalni materijali) ukazuje na novu mogućnost za primenu letećeg pepela. Za takvu primenu leteći pepeo mora da zadovolji visoke mehaničke i termičke kriterijume. Jedan od načina da se to postigne je mehanička aktivacija letećeg pepela. U ovom radu prikazani su rezultati mehaničke aktivacije pepela iz dve različite termo-elektrane pomoću planetarnog mlina. Aktivirani pepeli su mešani sa dva veziva: portland cementom i visoko-aluminatnim cementom. Akcenat je na analizi fizičko-hemijskih svojstava i mineroloških faza zbog promena koje se dešavaju u kompozitima usled mehaničke aktivacije pepela i sinterovanja. Makro svojstva kompozita su povezana sa mikrostrukturom ispitivanom pomoću SEM analize i Rendgenske difrakcije. Termijska stabilnost kristalnih faza ispitivana je pomoću DTA. Akcenat je na utvrđivanju korelacija između mehaničke aktivacije letećeg pepela i mikrostrukture kompozita na jednoj i svojstava sinterovanog kompozita na drugoj strani.
AB  - Amount of fly ash which is and yet to be generated in the coming years highlights the necessity of developing new methods of the recycling where this waste can be reused in significant quantity. A new possibility for fly ash utilization is in high-temperature application (thermal insulators or/and refractory material products). As such, fly ash has to adequately answer the mechanical and thermal stability criteria. One of the ways of achieving it is by applying mechanical activation procedure on fly ash. In present study, fly ashes from two different power plants were mechanically activated in a planetary ball mill. Mechanically treated fly ashes were cemented with two different binders: standard Portland cement and high-aluminates cement. Physico-chemical analysis and investigation of mineralogical components of composites are emphasized, due to the changes occurred in fly ash during mechanical activation and sintering of composites. Macro-performance of the composites was correlated to the microstructure of fly ash studied by means of XRD and SEM analysis. Thermal stability of crystalline phases was investigated with DTA. Highlight was placed on determination of relationship between mechanically activated fly ash and obtained composites microstructure on one side and behavior of sintered composites on the other side.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Synthesis and sintering of high-temperature composites based on mechanically activated fly ash
EP  - 146
IS  - 2
SP  - 135
VL  - 44
DO  - 10.2298/SOS1202135T
ER  - 

@article{
author = "Terzić, Anja and Pavlović, Ljubica and Obradović, Nina and Pavlović, Vladimir and Stojanović, Jovica and Miličić, Ljiljana and Radojević, Zagorka and Ristić, M.M.",
year = "2012",
abstract = "Količina letećeg pepela koji se proizvodi i koja će biti proizvedena u godinama koje dolaze zahteva razvoj novih metoda recikliranja u kojima će biti upotrebljene značajne količine ovog otpadnog materijala. Mogućnost visoko-temperaturne aplikacije (termoizolacioni i vatrostalni materijali) ukazuje na novu mogućnost za primenu letećeg pepela. Za takvu primenu leteći pepeo mora da zadovolji visoke mehaničke i termičke kriterijume. Jedan od načina da se to postigne je mehanička aktivacija letećeg pepela. U ovom radu prikazani su rezultati mehaničke aktivacije pepela iz dve različite termo-elektrane pomoću planetarnog mlina. Aktivirani pepeli su mešani sa dva veziva: portland cementom i visoko-aluminatnim cementom. Akcenat je na analizi fizičko-hemijskih svojstava i mineroloških faza zbog promena koje se dešavaju u kompozitima usled mehaničke aktivacije pepela i sinterovanja. Makro svojstva kompozita su povezana sa mikrostrukturom ispitivanom pomoću SEM analize i Rendgenske difrakcije. Termijska stabilnost kristalnih faza ispitivana je pomoću DTA. Akcenat je na utvrđivanju korelacija između mehaničke aktivacije letećeg pepela i mikrostrukture kompozita na jednoj i svojstava sinterovanog kompozita na drugoj strani., Amount of fly ash which is and yet to be generated in the coming years highlights the necessity of developing new methods of the recycling where this waste can be reused in significant quantity. A new possibility for fly ash utilization is in high-temperature application (thermal insulators or/and refractory material products). As such, fly ash has to adequately answer the mechanical and thermal stability criteria. One of the ways of achieving it is by applying mechanical activation procedure on fly ash. In present study, fly ashes from two different power plants were mechanically activated in a planetary ball mill. Mechanically treated fly ashes were cemented with two different binders: standard Portland cement and high-aluminates cement. Physico-chemical analysis and investigation of mineralogical components of composites are emphasized, due to the changes occurred in fly ash during mechanical activation and sintering of composites. Macro-performance of the composites was correlated to the microstructure of fly ash studied by means of XRD and SEM analysis. Thermal stability of crystalline phases was investigated with DTA. Highlight was placed on determination of relationship between mechanically activated fly ash and obtained composites microstructure on one side and behavior of sintered composites on the other side.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Synthesis and sintering of high-temperature composites based on mechanically activated fly ash",
pages = "146-135",
number = "2",
volume = "44",
doi = "10.2298/SOS1202135T"
}

Terzić, A., Pavlović, L., Obradović, N., Pavlović, V., Stojanović, J., Miličić, L., Radojević, Z.,& Ristić, M.M.. (2012). Synthesis and sintering of high-temperature composites based on mechanically activated fly ash. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 44(2), 135-146.
https://doi.org/10.2298/SOS1202135T

Terzić A, Pavlović L, Obradović N, Pavlović V, Stojanović J, Miličić L, Radojević Z, Ristić M. Synthesis and sintering of high-temperature composites based on mechanically activated fly ash. in Science of Sintering. 2012;44(2):135-146.
doi:10.2298/SOS1202135T .

Terzić, Anja, Pavlović, Ljubica, Obradović, Nina, Pavlović, Vladimir, Stojanović, Jovica, Miličić, Ljiljana, Radojević, Zagorka, Ristić, M.M., "Synthesis and sintering of high-temperature composites based on mechanically activated fly ash" in Science of Sintering, 44, no. 2 (2012):135-146,
https://doi.org/10.2298/SOS1202135T . .

TY  - JOUR
AU  - Prstić, Aurel
AU  - Aćimović-Pavlović, Zagorka
AU  - Andrić, Ljubiša
AU  - Stojanović, Jovica
AU  - Terzić, Anja
PY  - 2012
UR  - http://rims.institutims.rs/handle/123456789/194
AB  - U ovom radu je istraživana mogućnost dobijanja novih vatrostalnih premaza na bazi cirkona koji bi imali primenu u livarstvu. Optimizacija sastava premaza kontrolisana reološkim svojstvima postignuta je primenom različitih komponenata premaza, naročito primenom novog veziva na bazi suspenzije i variranjem načina spravljanja premaza. Čestice cirkonskoh praha veličine 25×10-6 m su korišćene kao ispuna. Uzorak cirkona ispitivan je pomoću sledećih metoda: difrakcija X-zraka, diferencijalna termalna analiza i mikroskopija. Oblik i veličina zrna su analizirani pomoću računarskog programa za analizu slike OZARIA 2.5. Pokazano je da primena ovih premaza na bazi vode i alkohola ima pozitivan uticaj na kvalitet površine, tj. na strukturne i mehaničke karakteristike odlivaka livenog gvožđa koji su dobijeni metodom livenja u peščane kalupe i pomoću isparljivih modela (Lost Foam metoda livenja).
AB  - In this work, a possibility to develop a new zircon-based refractory coating for casting applications was investigated. Optimization of the coating composition with controlled rheological properties was attained by application of different coating components, particularly by application of a new suspension agent and by alteration of coating production procedure. Zircon powder with particle size of 25×10-6 m was used as filler. The zircon sample was investigated by means of X-ray diffraction analysis, diffraction thermal analysis and polarized microscopy. The shape and grain size were analyzed using OZARIA 2.5 software. It was shown that application of this type of water-alcohol-based coating had a positive influence on surface quality, structural and mechanical properties of the castings of cast iron obtained by pouring into sand molds by means of the expandable patterns method (Lost Foam casting process).
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja
T1  - Zircon-based coating for the applications in Lost Foam casting process
EP  - 593
IS  - 4
SP  - 587
VL  - 18
DO  - 10.2298/CICEQ111122034P
ER  - 

@article{
author = "Prstić, Aurel and Aćimović-Pavlović, Zagorka and Andrić, Ljubiša and Stojanović, Jovica and Terzić, Anja",
year = "2012",
abstract = "U ovom radu je istraživana mogućnost dobijanja novih vatrostalnih premaza na bazi cirkona koji bi imali primenu u livarstvu. Optimizacija sastava premaza kontrolisana reološkim svojstvima postignuta je primenom različitih komponenata premaza, naročito primenom novog veziva na bazi suspenzije i variranjem načina spravljanja premaza. Čestice cirkonskoh praha veličine 25×10-6 m su korišćene kao ispuna. Uzorak cirkona ispitivan je pomoću sledećih metoda: difrakcija X-zraka, diferencijalna termalna analiza i mikroskopija. Oblik i veličina zrna su analizirani pomoću računarskog programa za analizu slike OZARIA 2.5. Pokazano je da primena ovih premaza na bazi vode i alkohola ima pozitivan uticaj na kvalitet površine, tj. na strukturne i mehaničke karakteristike odlivaka livenog gvožđa koji su dobijeni metodom livenja u peščane kalupe i pomoću isparljivih modela (Lost Foam metoda livenja)., In this work, a possibility to develop a new zircon-based refractory coating for casting applications was investigated. Optimization of the coating composition with controlled rheological properties was attained by application of different coating components, particularly by application of a new suspension agent and by alteration of coating production procedure. Zircon powder with particle size of 25×10-6 m was used as filler. The zircon sample was investigated by means of X-ray diffraction analysis, diffraction thermal analysis and polarized microscopy. The shape and grain size were analyzed using OZARIA 2.5 software. It was shown that application of this type of water-alcohol-based coating had a positive influence on surface quality, structural and mechanical properties of the castings of cast iron obtained by pouring into sand molds by means of the expandable patterns method (Lost Foam casting process).",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja, Zircon-based coating for the applications in Lost Foam casting process",
pages = "593-587",
number = "4",
volume = "18",
doi = "10.2298/CICEQ111122034P"
}

Prstić, A., Aćimović-Pavlović, Z., Andrić, L., Stojanović, J.,& Terzić, A.. (2012). Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Savez hemijskih inženjera, Beograd., 18(4), 587-593.
https://doi.org/10.2298/CICEQ111122034P

Prstić A, Aćimović-Pavlović Z, Andrić L, Stojanović J, Terzić A. Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2012;18(4):587-593.
doi:10.2298/CICEQ111122034P .

Prstić, Aurel, Aćimović-Pavlović, Zagorka, Andrić, Ljubiša, Stojanović, Jovica, Terzić, Anja, "Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 18, no. 4 (2012):587-593,
https://doi.org/10.2298/CICEQ111122034P . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
AU  - Stojanović, Jovica
AU  - Radojević, Zagorka
PY  - 2012
UR  - http://rims.institutims.rs/handle/123456789/167
AB  - Konstrukcioni kompoziti - termo-izolaciona i/ili visoko-temperaturna veziva u kojima je leteći pepeo, kao potencijalno štetna materija za okolinu, kombinovan sa običnim i vatrostalnim cementom predstavlja jednu sasvim novu mogućnost za reaplikaciju ovog otpadnog materijala. U ovoj studiji, ispitivana su veziva spravljena na bazi dve vrste letećeg pepela dobijenog procesom sagorevanja uglja i dve vrste cementa - obični Portland cement i visoko-aluminatni cement. Promena u mineralnom sastavu kompozita uslovljena povećanjem temperature je analizirana pomoću XRD metode. Mikrostrukturne promene ispitivanih kompozita su utvrđene na osnovu rezultata skening-elektronske mikroskopije (SEM). Makro performanse - mehanička svojstva ispitivanih veziva su povezana sa promenama koje se dešavaju u mikrostrukturi materijala. Ispitivana veziva imaju odlične vrednosti pritisne čvrsoće, a SEM i XRD analiza je ukazala i na potencijalno dobra termo-izolaciona i vatrostalna svojstva ovih materijala.
AB  - Building composites - thermo-insulating and/or high-temperature resistant bonding agents in which fly ash, as potentially environmentally harmful waste material, is combined with ordinary and refractory cement is new option for reapplication of this waste material. In this study, investigated bonding agents were based on two types of fly ashes from coal combustion process and cements - ordinary Portland cement and highaluminate cement. Change of mineral phase composition of the composites with increasing temperature was analyzed by means of XRD method. Microstructural changes within investigated composites were investigated by means of scanning electron microscopy (SEM). Macro-performance - mechanical properties of the investigated bonding agents was finally correlated with its microstructure. The investigated bonding agents showed excellent compressive strength, while SEM and XRD analysis indicated its valuable refractory and thermo-insulation properties.
PB  - Univerzitet u Nišu, Niš
T2  - Facta universitatis - series: Architecture and Civil Engineering
T1  - Veza između mikrostrukture, faznog sastava i mehaničkih svojstava termo-izolacionih veziva na bazi otpadnog materijala
T1  - Correlation between microstructure, phase composition and mechanical properties of thermo-insulation bonding agents based on waste material
EP  - 258
IS  - 3
SP  - 245
VL  - 10
DO  - 10.2298/FUACE1203245T
ER  - 

@article{
author = "Terzić, Anja and Pavlović, Ljubica and Stojanović, Jovica and Radojević, Zagorka",
year = "2012",
abstract = "Konstrukcioni kompoziti - termo-izolaciona i/ili visoko-temperaturna veziva u kojima je leteći pepeo, kao potencijalno štetna materija za okolinu, kombinovan sa običnim i vatrostalnim cementom predstavlja jednu sasvim novu mogućnost za reaplikaciju ovog otpadnog materijala. U ovoj studiji, ispitivana su veziva spravljena na bazi dve vrste letećeg pepela dobijenog procesom sagorevanja uglja i dve vrste cementa - obični Portland cement i visoko-aluminatni cement. Promena u mineralnom sastavu kompozita uslovljena povećanjem temperature je analizirana pomoću XRD metode. Mikrostrukturne promene ispitivanih kompozita su utvrđene na osnovu rezultata skening-elektronske mikroskopije (SEM). Makro performanse - mehanička svojstva ispitivanih veziva su povezana sa promenama koje se dešavaju u mikrostrukturi materijala. Ispitivana veziva imaju odlične vrednosti pritisne čvrsoće, a SEM i XRD analiza je ukazala i na potencijalno dobra termo-izolaciona i vatrostalna svojstva ovih materijala., Building composites - thermo-insulating and/or high-temperature resistant bonding agents in which fly ash, as potentially environmentally harmful waste material, is combined with ordinary and refractory cement is new option for reapplication of this waste material. In this study, investigated bonding agents were based on two types of fly ashes from coal combustion process and cements - ordinary Portland cement and highaluminate cement. Change of mineral phase composition of the composites with increasing temperature was analyzed by means of XRD method. Microstructural changes within investigated composites were investigated by means of scanning electron microscopy (SEM). Macro-performance - mechanical properties of the investigated bonding agents was finally correlated with its microstructure. The investigated bonding agents showed excellent compressive strength, while SEM and XRD analysis indicated its valuable refractory and thermo-insulation properties.",
publisher = "Univerzitet u Nišu, Niš",
journal = "Facta universitatis - series: Architecture and Civil Engineering",
title = "Veza između mikrostrukture, faznog sastava i mehaničkih svojstava termo-izolacionih veziva na bazi otpadnog materijala, Correlation between microstructure, phase composition and mechanical properties of thermo-insulation bonding agents based on waste material",
pages = "258-245",
number = "3",
volume = "10",
doi = "10.2298/FUACE1203245T"
}

Terzić, A., Pavlović, L., Stojanović, J.,& Radojević, Z.. (2012). Veza između mikrostrukture, faznog sastava i mehaničkih svojstava termo-izolacionih veziva na bazi otpadnog materijala. in Facta universitatis - series: Architecture and Civil Engineering
Univerzitet u Nišu, Niš., 10(3), 245-258.
https://doi.org/10.2298/FUACE1203245T

Terzić A, Pavlović L, Stojanović J, Radojević Z. Veza između mikrostrukture, faznog sastava i mehaničkih svojstava termo-izolacionih veziva na bazi otpadnog materijala. in Facta universitatis - series: Architecture and Civil Engineering. 2012;10(3):245-258.
doi:10.2298/FUACE1203245T .

Terzić, Anja, Pavlović, Ljubica, Stojanović, Jovica, Radojević, Zagorka, "Veza između mikrostrukture, faznog sastava i mehaničkih svojstava termo-izolacionih veziva na bazi otpadnog materijala" in Facta universitatis - series: Architecture and Civil Engineering, 10, no. 3 (2012):245-258,
https://doi.org/10.2298/FUACE1203245T . .