Miličić, Ljiljana

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Authority KeyName Variants
orcid::0000-0002-3002-7058
  • Miličić, Ljiljana (35)
Projects
Directed synthesis, structure and properties of multifunctional materials Development and application of multifunctional materials using domestic raw materials in upgraded processing lines
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200012 (Istitute of Material Testing of Serbia - IMS, Belgrade) Utilization of by-products and recycled waste materials in concrete composites in the scope of sustainable construction development in Serbia: investigation and environmental assessment of possible applications
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Osvajanje procesa za proizvodnju metakaolina, karakterizacija dobijenog proizvoda i efekti njegove primene na karakteristike cementa
Ministry of Education, Science and Technological Development of the Republic of Serbia Australian Nuclear Science and Technology Organisation (ANSTO)
Oxide-based environmentally-friendly porous materials for genotoxic substances removal Urbanisation Processes and Development of Mediaeval Society
Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes Osmotic dehydration of food - energy and ecological aspects of sustainable production
Implementation of new technical, technological and environmental solutions in the mining and metallurgical operations RBB and RBM Mechanochemistry treatment of low quality mineral raw materials
Cleaner production: power plant wastewater treatment process development Development of technological processes for obtaining of ecological materials based on nonmetallic minerals
Serbian Academy of Sciences and Arts F-198 Serbian Ministry of Education and ScienceMinistry of Education, Science & Technological Development, Serbia

Author's Bibliography

Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives

Mijatović, Nevenka; Terzić, Anja; Miličić, Ljiljana

(2023)

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Miličić, Ljiljana
PY  - 2023
UR  - http://rims.institutims.rs/handle/123456789/488
AB  - Natural zeolite and bentonite were used as mineral addi-tions to create cement-based building materials that are safe for the environment. This research focuses on the adsorptive qualities of these two clay raw materials, i.e., their propen-sity to immobilize heavy metal ions like Cd2+. The acquired results were examined using kinetic models of pseudo-first and pseudo-second order. The isotherms of Langmuir and Freundlich were examined. Zeolite and bentonite had differ-ent adsorption affinities for Cd2+ cations. Seven cement binders with various mineral additions (fly ash, zeolite, bentonite) underwent a leaching test. The adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites caused leachates obtained on cement samples with the addition of fly ash and clay (either zeolite or bentonite) to contain lower concentrations of Cd2+ ions than leachates obtained on cement samples with fly ash alone.
T2  - Structural Integrity and Life, Special Issue
T1  - Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives
EP  - 24
SP  - 19
VL  - 23
UR  - https://hdl.handle.net/21.15107/rcub_rims_488
ER  - 
@article{
author = "Mijatović, Nevenka and Terzić, Anja and Miličić, Ljiljana",
year = "2023",
abstract = "Natural zeolite and bentonite were used as mineral addi-tions to create cement-based building materials that are safe for the environment. This research focuses on the adsorptive qualities of these two clay raw materials, i.e., their propen-sity to immobilize heavy metal ions like Cd2+. The acquired results were examined using kinetic models of pseudo-first and pseudo-second order. The isotherms of Langmuir and Freundlich were examined. Zeolite and bentonite had differ-ent adsorption affinities for Cd2+ cations. Seven cement binders with various mineral additions (fly ash, zeolite, bentonite) underwent a leaching test. The adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites caused leachates obtained on cement samples with the addition of fly ash and clay (either zeolite or bentonite) to contain lower concentrations of Cd2+ ions than leachates obtained on cement samples with fly ash alone.",
journal = "Structural Integrity and Life, Special Issue",
title = "Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives",
pages = "24-19",
volume = "23",
url = "https://hdl.handle.net/21.15107/rcub_rims_488"
}
Mijatović, N., Terzić, A.,& Miličić, L.. (2023). Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives. in Structural Integrity and Life, Special Issue, 23, 19-24.
https://hdl.handle.net/21.15107/rcub_rims_488
Mijatović N, Terzić A, Miličić L. Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives. in Structural Integrity and Life, Special Issue. 2023;23:19-24.
https://hdl.handle.net/21.15107/rcub_rims_488 .
Mijatović, Nevenka, Terzić, Anja, Miličić, Ljiljana, "Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives" in Structural Integrity and Life, Special Issue, 23 (2023):19-24,
https://hdl.handle.net/21.15107/rcub_rims_488 .

Fired pressed pellet as a sample preparation technique of choice for an energy dispersive X-ray fluorescence analysis of raw clays

Mijatović, Nevenka; Vasić, Milica; Miličić, Ljiljana; Radomirović, Milena; Radojević, Zagorka

(Elsevier, 2022)

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Vasić, Milica
AU  - Miličić, Ljiljana
AU  - Radomirović, Milena
AU  - Radojević, Zagorka
PY  - 2022
UR  - http://rims.institutims.rs/handle/123456789/427
AB  - In this paper, the main subject concerns comparing different techniques to prepare raw clay samples for energy dispersive X-ray fluorescence spectrometry (EDXRF). Three kinds of sample preparation procedures are examined,such as loose powder, pressed pellet, and fired pressed pellet. The fired pressed pellet approach was observed as a part of universal sample preparation for physic, mechanical, and instrumental analysis, which has not been previously tested as a solution in chemical analysis by the EDXRF method. The observed sample preparation techniques were compared by calculating the parameters of validation (recoveries, limit of detection-LOD, limit of quantification - LOQ, precision, and expanded uncertainties of measurements) of 11 elements (Si, Al, Fe, Ca, Mg, K, Na, Ti, P, Mn, and S) using 15 certified reference materials (CRMs). Calibration curves were created and evaluated using 30 reference materials (RM) for all three approaches. Results proved that the fired pressed pellet is the most practical and precise approach for sample preparation of raw clays.
PB  - Elsevier
T2  - Talanta
T1  - Fired pressed pellet as a sample preparation technique of choice for an energy dispersive X-ray fluorescence analysis of raw clays
VL  - 252
DO  - https://doi.org/10.1016/j.talanta.2022.123844
ER  - 
@article{
author = "Mijatović, Nevenka and Vasić, Milica and Miličić, Ljiljana and Radomirović, Milena and Radojević, Zagorka",
year = "2022",
abstract = "In this paper, the main subject concerns comparing different techniques to prepare raw clay samples for energy dispersive X-ray fluorescence spectrometry (EDXRF). Three kinds of sample preparation procedures are examined,such as loose powder, pressed pellet, and fired pressed pellet. The fired pressed pellet approach was observed as a part of universal sample preparation for physic, mechanical, and instrumental analysis, which has not been previously tested as a solution in chemical analysis by the EDXRF method. The observed sample preparation techniques were compared by calculating the parameters of validation (recoveries, limit of detection-LOD, limit of quantification - LOQ, precision, and expanded uncertainties of measurements) of 11 elements (Si, Al, Fe, Ca, Mg, K, Na, Ti, P, Mn, and S) using 15 certified reference materials (CRMs). Calibration curves were created and evaluated using 30 reference materials (RM) for all three approaches. Results proved that the fired pressed pellet is the most practical and precise approach for sample preparation of raw clays.",
publisher = "Elsevier",
journal = "Talanta",
title = "Fired pressed pellet as a sample preparation technique of choice for an energy dispersive X-ray fluorescence analysis of raw clays",
volume = "252",
doi = "https://doi.org/10.1016/j.talanta.2022.123844"
}
Mijatović, N., Vasić, M., Miličić, L., Radomirović, M.,& Radojević, Z.. (2022). Fired pressed pellet as a sample preparation technique of choice for an energy dispersive X-ray fluorescence analysis of raw clays. in Talanta
Elsevier., 252.
https://doi.org/https://doi.org/10.1016/j.talanta.2022.123844
Mijatović N, Vasić M, Miličić L, Radomirović M, Radojević Z. Fired pressed pellet as a sample preparation technique of choice for an energy dispersive X-ray fluorescence analysis of raw clays. in Talanta. 2022;252.
doi:https://doi.org/10.1016/j.talanta.2022.123844 .
Mijatović, Nevenka, Vasić, Milica, Miličić, Ljiljana, Radomirović, Milena, Radojević, Zagorka, "Fired pressed pellet as a sample preparation technique of choice for an energy dispersive X-ray fluorescence analysis of raw clays" in Talanta, 252 (2022),
https://doi.org/https://doi.org/10.1016/j.talanta.2022.123844 . .

Assessment of Efficiency of Rare Earth Elements Recovery from Lignite Coal Combustion Ash via Five-Stage Extraction

Miličić, Ljiljana; Terzić, Anja; Pezo, Lato; Mijatović, Nevenka; Brceski, Ilija; Vukelić, Nikola

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2021)

TY  - JOUR
AU  - Miličić, Ljiljana
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Mijatović, Nevenka
AU  - Brceski, Ilija
AU  - Vukelić, Nikola
PY  - 2021
UR  - http://rims.institutims.rs/handle/123456789/400
AB  - Rare earth elements (REE) are frequently referred to as ingredients for enhancements in modem industry, as they are extensively applied in many industrial branches due to their accented electro-magnetic and optical properties. REE have end-utilizations as catalysts, magnets, and as dopants for ceramic materials. Rare earth minerals are scarce therefore the unconventional REE-containing resources such as waste materials and industrial byproducts are continuously being investigated. Coal combustion products comprise REE concentrations varying between 200 ppm and 1500 ppm. This quantity can be isolated though the extraction procedure. In this study, the five stages extraction was conducted on the coal combustion ash from the selected landfill site. The extractions of 32 elements (As, Ga, Ce, Be, Ge, Nd, Cr, Zr, Eu, Cu, Nb, Gd, Co, Mo, Dy, Li, Ag, W, Mn, Cd, Au, Ni, In, Hg, Pb, Sn, Ti, V, Sb, Th, Zn, and La) were conveyed. Chemical analyses were conducted via XRF, ICP-OES, ICP-MS, and MS techniques. The complexity of the obtained data was examined by Principal component analysis and Cluster analysis in order to derive interconnections between quantity of elements and landfill characteristics, as well as mutual relationships among the elements of interest, and to assess the accomplishment of REE recovery from the coal ash.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Assessment of Efficiency of Rare Earth Elements Recovery from Lignite Coal Combustion Ash via Five-Stage Extraction
EP  - 185
IS  - 2
SP  - 169
VL  - 53
DO  - 10.2298/SOS2102169M
ER  - 
@article{
author = "Miličić, Ljiljana and Terzić, Anja and Pezo, Lato and Mijatović, Nevenka and Brceski, Ilija and Vukelić, Nikola",
year = "2021",
abstract = "Rare earth elements (REE) are frequently referred to as ingredients for enhancements in modem industry, as they are extensively applied in many industrial branches due to their accented electro-magnetic and optical properties. REE have end-utilizations as catalysts, magnets, and as dopants for ceramic materials. Rare earth minerals are scarce therefore the unconventional REE-containing resources such as waste materials and industrial byproducts are continuously being investigated. Coal combustion products comprise REE concentrations varying between 200 ppm and 1500 ppm. This quantity can be isolated though the extraction procedure. In this study, the five stages extraction was conducted on the coal combustion ash from the selected landfill site. The extractions of 32 elements (As, Ga, Ce, Be, Ge, Nd, Cr, Zr, Eu, Cu, Nb, Gd, Co, Mo, Dy, Li, Ag, W, Mn, Cd, Au, Ni, In, Hg, Pb, Sn, Ti, V, Sb, Th, Zn, and La) were conveyed. Chemical analyses were conducted via XRF, ICP-OES, ICP-MS, and MS techniques. The complexity of the obtained data was examined by Principal component analysis and Cluster analysis in order to derive interconnections between quantity of elements and landfill characteristics, as well as mutual relationships among the elements of interest, and to assess the accomplishment of REE recovery from the coal ash.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Assessment of Efficiency of Rare Earth Elements Recovery from Lignite Coal Combustion Ash via Five-Stage Extraction",
pages = "185-169",
number = "2",
volume = "53",
doi = "10.2298/SOS2102169M"
}
Miličić, L., Terzić, A., Pezo, L., Mijatović, N., Brceski, I.,& Vukelić, N.. (2021). Assessment of Efficiency of Rare Earth Elements Recovery from Lignite Coal Combustion Ash via Five-Stage Extraction. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 53(2), 169-185.
https://doi.org/10.2298/SOS2102169M
Miličić L, Terzić A, Pezo L, Mijatović N, Brceski I, Vukelić N. Assessment of Efficiency of Rare Earth Elements Recovery from Lignite Coal Combustion Ash via Five-Stage Extraction. in Science of Sintering. 2021;53(2):169-185.
doi:10.2298/SOS2102169M .
Miličić, Ljiljana, Terzić, Anja, Pezo, Lato, Mijatović, Nevenka, Brceski, Ilija, Vukelić, Nikola, "Assessment of Efficiency of Rare Earth Elements Recovery from Lignite Coal Combustion Ash via Five-Stage Extraction" in Science of Sintering, 53, no. 2 (2021):169-185,
https://doi.org/10.2298/SOS2102169M . .
2
2

Cavitation Properties of Rendering Mortars with Micro Silica Addition

Terzić, Anja; Dojčinović, Marina; Miličić, Ljiljana; Stojanović, Jovica; Radojević, Zagorka

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2021)

TY  - JOUR
AU  - Terzić, Anja
AU  - Dojčinović, Marina
AU  - Miličić, Ljiljana
AU  - Stojanović, Jovica
AU  - Radojević, Zagorka
PY  - 2021
UR  - http://rims.institutims.rs/handle/123456789/399
AB  - Micro-silica is a highly efficient mineral additive whose role is reflected in improvements of microstructure packing, strength and durability of non-shaped composite building materials such as concrete and mortar. A comparative study of performances of rendering mortars with different quantities of micro silica was conducted. The experimental program included production of reference mortar based on Portland cement and quartz sand (CM) and three mortars with 5, 10, and 15 % addition of micro silica (SCM-5, SCM-10, and SCM-15). The effect that micro silica addition has on the thermal behavior and mechanical properties of mortars was discussed. Hydration mechanisms and thermally induced reactions were studied at temperatures ranging from ambient to 1100 degrees C by differential thermal analysis. The results were supported by X-ray diffraction analysis. The cementing efficiency of micro silica was assessed by cavitation erosion test. The changes in the morphology of mortar samples prior and upon cavitation testing were monitored by means of the scanning electron microscope imagining. It was found that 5 % of superfine micro silica (SCM-5 mortar) has positive effects on mechanical strengths (15 % increase in compressive strength) due to microstructure densification arising from the successive filling of voids by the micro silica. Addition of micro silica also improved the cavitation erosion resistance in comparison with reference cement mortar (SCM-5 showed cavitation velocity as low as 0.09 mg/min). This qualifies mortars with micro silica addition as building materials which can be safely employed in potential hydro-demolition environment.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Cavitation Properties of Rendering Mortars with Micro Silica Addition
EP  - 459
IS  - 4
SP  - 445
VL  - 53
DO  - 10.2298/SOS2104445T
ER  - 
@article{
author = "Terzić, Anja and Dojčinović, Marina and Miličić, Ljiljana and Stojanović, Jovica and Radojević, Zagorka",
year = "2021",
abstract = "Micro-silica is a highly efficient mineral additive whose role is reflected in improvements of microstructure packing, strength and durability of non-shaped composite building materials such as concrete and mortar. A comparative study of performances of rendering mortars with different quantities of micro silica was conducted. The experimental program included production of reference mortar based on Portland cement and quartz sand (CM) and three mortars with 5, 10, and 15 % addition of micro silica (SCM-5, SCM-10, and SCM-15). The effect that micro silica addition has on the thermal behavior and mechanical properties of mortars was discussed. Hydration mechanisms and thermally induced reactions were studied at temperatures ranging from ambient to 1100 degrees C by differential thermal analysis. The results were supported by X-ray diffraction analysis. The cementing efficiency of micro silica was assessed by cavitation erosion test. The changes in the morphology of mortar samples prior and upon cavitation testing were monitored by means of the scanning electron microscope imagining. It was found that 5 % of superfine micro silica (SCM-5 mortar) has positive effects on mechanical strengths (15 % increase in compressive strength) due to microstructure densification arising from the successive filling of voids by the micro silica. Addition of micro silica also improved the cavitation erosion resistance in comparison with reference cement mortar (SCM-5 showed cavitation velocity as low as 0.09 mg/min). This qualifies mortars with micro silica addition as building materials which can be safely employed in potential hydro-demolition environment.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Cavitation Properties of Rendering Mortars with Micro Silica Addition",
pages = "459-445",
number = "4",
volume = "53",
doi = "10.2298/SOS2104445T"
}
Terzić, A., Dojčinović, M., Miličić, L., Stojanović, J.,& Radojević, Z.. (2021). Cavitation Properties of Rendering Mortars with Micro Silica Addition. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 53(4), 445-459.
https://doi.org/10.2298/SOS2104445T
Terzić A, Dojčinović M, Miličić L, Stojanović J, Radojević Z. Cavitation Properties of Rendering Mortars with Micro Silica Addition. in Science of Sintering. 2021;53(4):445-459.
doi:10.2298/SOS2104445T .
Terzić, Anja, Dojčinović, Marina, Miličić, Ljiljana, Stojanović, Jovica, Radojević, Zagorka, "Cavitation Properties of Rendering Mortars with Micro Silica Addition" in Science of Sintering, 53, no. 4 (2021):445-459,
https://doi.org/10.2298/SOS2104445T . .

Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa

Mijatović, Nevenka; Terzić, Anja; Miličić, Ljiljana; Živojinović, Dragana

(Inženjersko društvo za koroziju, Beograd, 2020)

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Miličić, Ljiljana
AU  - Živojinović, Dragana
PY  - 2020
UR  - http://rims.institutims.rs/handle/123456789/388
AB  - Prirodni zeolit i bentonit korišćeni su kao mineralni dodaci u mešavinskom dizajnu ekološki sigurnih građevinskih materijala na bazi cementa. Ispitane su adsorptivne sposobnosti ove dve glinene sirovine, tj. njihov afinitet da imobiliziraju jone teških metala Zn2+, Ni2+, Pb2+ i Cu2+. Za eksperiment su pripremljeni pojedinačni i multi-rastvori Zn2+, Ni2+, Pb2+ i Cu2+ . Dobijeni rezultati su analizirani pomoću kinetičkih modela pseudo prvog i pseudo drugog reda. Analizirane su izoterme Langmuira i Freundlicha. Bentonit je pokazao bolji adsorpcioni afinitet od zeolita prema sva četiri ispitivana katjona. Kao dokaz, ispitano je ispitivanje ispiranja na sedam različitih veziva za cement sa različitim mineralnim dodacima (leteći pepeo, zeolit, bentonit). Eluati dobijeni na uzorcima cementa sa dodatkom letećeg pepela i gline (bilo zeolita ili bentonita) sadržavale su niže koncentracije jona Zn2+, Ni2+, Pb2+ i Cu2+ u odnosu na eluat dobijen na uzorcima cementnog veziva sa letećim pepelom. Razlog za dobijanje ovakvih rezultata su adsorpcioni i hidratacioni mehanizmi koji imobiliziraju teške metale u cementnim kompozitima.
AB  - Natural zeolite and bentonite were utilized as mineral additives in the mix-design of environmentally safe cement-based building materials. The adsorptive abilities of these two clayey raw materials, i.e. their affinity to immobilize heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ were investigated. Singleand multi-solutions of Zn2+, Ni2+, Pb2+ and Cu2+ were prepared for the experiment. The obtained results were submitted to analysis via pseudo-first and pseudo-second order kinetic models. Langmuir and Freundlich isotherms were analyzed. Bentonite exhibited better adsorption affinity than zeolite towards all four investigated cations. As a proof, a leaching test was conducted on seven different cement binders with different mineral additives (fly ash, zeolite, bentonite). The leachates obtained on the samples of cement with addition of fly ash and clay (either zeolite or bentonite) contained lower concentrations of Zn2+, Ni2+, Pb2+ and Cu2+ ions than leachates obtained on the samples of cement binder with fly ash solely as a result of adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites.
PB  - Inženjersko društvo za koroziju, Beograd
T2  - Zaštita materijala
T1  - Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa
T1  - Immobilization of heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ in the structure of cement-based materials
EP  - 127
IS  - 2
SP  - 116
VL  - 61
DO  - 10.5937/zasmat2002116M
ER  - 
@article{
author = "Mijatović, Nevenka and Terzić, Anja and Miličić, Ljiljana and Živojinović, Dragana",
year = "2020",
abstract = "Prirodni zeolit i bentonit korišćeni su kao mineralni dodaci u mešavinskom dizajnu ekološki sigurnih građevinskih materijala na bazi cementa. Ispitane su adsorptivne sposobnosti ove dve glinene sirovine, tj. njihov afinitet da imobiliziraju jone teških metala Zn2+, Ni2+, Pb2+ i Cu2+. Za eksperiment su pripremljeni pojedinačni i multi-rastvori Zn2+, Ni2+, Pb2+ i Cu2+ . Dobijeni rezultati su analizirani pomoću kinetičkih modela pseudo prvog i pseudo drugog reda. Analizirane su izoterme Langmuira i Freundlicha. Bentonit je pokazao bolji adsorpcioni afinitet od zeolita prema sva četiri ispitivana katjona. Kao dokaz, ispitano je ispitivanje ispiranja na sedam različitih veziva za cement sa različitim mineralnim dodacima (leteći pepeo, zeolit, bentonit). Eluati dobijeni na uzorcima cementa sa dodatkom letećeg pepela i gline (bilo zeolita ili bentonita) sadržavale su niže koncentracije jona Zn2+, Ni2+, Pb2+ i Cu2+ u odnosu na eluat dobijen na uzorcima cementnog veziva sa letećim pepelom. Razlog za dobijanje ovakvih rezultata su adsorpcioni i hidratacioni mehanizmi koji imobiliziraju teške metale u cementnim kompozitima., Natural zeolite and bentonite were utilized as mineral additives in the mix-design of environmentally safe cement-based building materials. The adsorptive abilities of these two clayey raw materials, i.e. their affinity to immobilize heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ were investigated. Singleand multi-solutions of Zn2+, Ni2+, Pb2+ and Cu2+ were prepared for the experiment. The obtained results were submitted to analysis via pseudo-first and pseudo-second order kinetic models. Langmuir and Freundlich isotherms were analyzed. Bentonite exhibited better adsorption affinity than zeolite towards all four investigated cations. As a proof, a leaching test was conducted on seven different cement binders with different mineral additives (fly ash, zeolite, bentonite). The leachates obtained on the samples of cement with addition of fly ash and clay (either zeolite or bentonite) contained lower concentrations of Zn2+, Ni2+, Pb2+ and Cu2+ ions than leachates obtained on the samples of cement binder with fly ash solely as a result of adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites.",
publisher = "Inženjersko društvo za koroziju, Beograd",
journal = "Zaštita materijala",
title = "Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa, Immobilization of heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ in the structure of cement-based materials",
pages = "127-116",
number = "2",
volume = "61",
doi = "10.5937/zasmat2002116M"
}
Mijatović, N., Terzić, A., Miličić, L.,& Živojinović, D.. (2020). Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa. in Zaštita materijala
Inženjersko društvo za koroziju, Beograd., 61(2), 116-127.
https://doi.org/10.5937/zasmat2002116M
Mijatović N, Terzić A, Miličić L, Živojinović D. Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa. in Zaštita materijala. 2020;61(2):116-127.
doi:10.5937/zasmat2002116M .
Mijatović, Nevenka, Terzić, Anja, Miličić, Ljiljana, Živojinović, Dragana, "Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa" in Zaštita materijala, 61, no. 2 (2020):116-127,
https://doi.org/10.5937/zasmat2002116M . .
1

Improvement and modification of the energy-dispersive X-ray fluorescence method for the determination of metal elements in cement leachates - A chemometric approach

Mijatović, Nevenka; Terzić, Anja; Pezo, Lato; Miličić, Ljiljana; Živojinović, Dragana

(Srpsko hemijsko društvo, Beograd, 2020)

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Miličić, Ljiljana
AU  - Živojinović, Dragana
PY  - 2020
UR  - http://rims.institutims.rs/handle/123456789/377
AB  - A modification of an analytical procedure for the energy-dispersive X-ray fluorescence (EDXRF) quantification of ten chemical elements (As, Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb and Zn) in the leachates obtained from cement binders was developed. Twenty-nine testing samples were used in the experiment. All samples were based on Portland cement. Fly ash of different origin, zeolite and bentonite were employed as mineral additives in the cement binders. Distilled water was used as the leachate. Validation of the modified EDXRF procedure was conducted in terms of limits of detection and quantification, working range, linearity, selectivity, precision, trueness, and robustness. Traceability of the procedure was established using certified reference materials. Uncertainty of measurement was confirmed via an "in-house" laboratory validation approach. The expanded uncertainties for the ten analysed elements were obtained for the entire working range of the EDXRF method. Robustness of the modified EDXRF procedure was assessed by means of a chemometric in-house approach. The results obtained by the modified X-ray fluorescence method were additionally correlated to those acquired by inductively coupled plasma optical emission spectrometry to confirm that EDXRF could be used as an effective and reliable alternative method for analysis of cement leachates.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Improvement and modification of the energy-dispersive X-ray fluorescence method for the determination of metal elements in cement leachates - A chemometric approach
EP  - 1619
IS  - 12
SP  - 1605
VL  - 85
DO  - 10.2298/JSC200501067M
ER  - 
@article{
author = "Mijatović, Nevenka and Terzić, Anja and Pezo, Lato and Miličić, Ljiljana and Živojinović, Dragana",
year = "2020",
abstract = "A modification of an analytical procedure for the energy-dispersive X-ray fluorescence (EDXRF) quantification of ten chemical elements (As, Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb and Zn) in the leachates obtained from cement binders was developed. Twenty-nine testing samples were used in the experiment. All samples were based on Portland cement. Fly ash of different origin, zeolite and bentonite were employed as mineral additives in the cement binders. Distilled water was used as the leachate. Validation of the modified EDXRF procedure was conducted in terms of limits of detection and quantification, working range, linearity, selectivity, precision, trueness, and robustness. Traceability of the procedure was established using certified reference materials. Uncertainty of measurement was confirmed via an "in-house" laboratory validation approach. The expanded uncertainties for the ten analysed elements were obtained for the entire working range of the EDXRF method. Robustness of the modified EDXRF procedure was assessed by means of a chemometric in-house approach. The results obtained by the modified X-ray fluorescence method were additionally correlated to those acquired by inductively coupled plasma optical emission spectrometry to confirm that EDXRF could be used as an effective and reliable alternative method for analysis of cement leachates.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Improvement and modification of the energy-dispersive X-ray fluorescence method for the determination of metal elements in cement leachates - A chemometric approach",
pages = "1619-1605",
number = "12",
volume = "85",
doi = "10.2298/JSC200501067M"
}
Mijatović, N., Terzić, A., Pezo, L., Miličić, L.,& Živojinović, D.. (2020). Improvement and modification of the energy-dispersive X-ray fluorescence method for the determination of metal elements in cement leachates - A chemometric approach. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 85(12), 1605-1619.
https://doi.org/10.2298/JSC200501067M
Mijatović N, Terzić A, Pezo L, Miličić L, Živojinović D. Improvement and modification of the energy-dispersive X-ray fluorescence method for the determination of metal elements in cement leachates - A chemometric approach. in Journal of the Serbian Chemical Society. 2020;85(12):1605-1619.
doi:10.2298/JSC200501067M .
Mijatović, Nevenka, Terzić, Anja, Pezo, Lato, Miličić, Ljiljana, Živojinović, Dragana, "Improvement and modification of the energy-dispersive X-ray fluorescence method for the determination of metal elements in cement leachates - A chemometric approach" in Journal of the Serbian Chemical Society, 85, no. 12 (2020):1605-1619,
https://doi.org/10.2298/JSC200501067M . .
1
1

Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes

Terzić, Anja; Stojanović, Jovica; Andrić, Ljubiša; Miličić, Ljiljana; Radojević, Zagorka

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2020)

TY  - JOUR
AU  - Terzić, Anja
AU  - Stojanović, Jovica
AU  - Andrić, Ljubiša
AU  - Miličić, Ljiljana
AU  - Radojević, Zagorka
PY  - 2020
UR  - http://rims.institutims.rs/handle/123456789/390
AB  - This experimental study was conducted with an aim to investigate the effect of the elevated temperature on the mineral phase composition, microstructure and mechanical properties of the thermal insulation lightweight concretes. The first group of experimental concretes was based on the expanded vermiculite and expanded perlite used as lightweight aggregates (in 65 wt%) in combination with either ordinary Portland cement or refractory calcium aluminate cement. The mix-design of the second group of concretes comprised standard quartz aggregate, vermiculite or perlite as aggregate replacement (25 wt%) and binder (PC or CAC). A total of 10 concrete mix-designs were fabricated in form of 40x40x160 mm samples which were submitted to heat-treatment at 400 degrees, 600 degrees, 800 degrees and 1000 degrees C upon standard 28-days period of curing and hardening. The changes in crystallinity and mineral phase composition induced by temperature were monitored by X-ray diffraction technique. Microstructural visualizations of the non-fired and fired concrete samples were conducted by scanning electron microscopy accompanied with EDX analysis. The results indicated that despite the decrease in compressive strengths upon firing, investigated lightweight concretes can be categorized both as thermal insulators and structural materials.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes
EP  - 162
IS  - 2
SP  - 149
VL  - 52
DO  - 10.2298/SOS2002149T
ER  - 
@article{
author = "Terzić, Anja and Stojanović, Jovica and Andrić, Ljubiša and Miličić, Ljiljana and Radojević, Zagorka",
year = "2020",
abstract = "This experimental study was conducted with an aim to investigate the effect of the elevated temperature on the mineral phase composition, microstructure and mechanical properties of the thermal insulation lightweight concretes. The first group of experimental concretes was based on the expanded vermiculite and expanded perlite used as lightweight aggregates (in 65 wt%) in combination with either ordinary Portland cement or refractory calcium aluminate cement. The mix-design of the second group of concretes comprised standard quartz aggregate, vermiculite or perlite as aggregate replacement (25 wt%) and binder (PC or CAC). A total of 10 concrete mix-designs were fabricated in form of 40x40x160 mm samples which were submitted to heat-treatment at 400 degrees, 600 degrees, 800 degrees and 1000 degrees C upon standard 28-days period of curing and hardening. The changes in crystallinity and mineral phase composition induced by temperature were monitored by X-ray diffraction technique. Microstructural visualizations of the non-fired and fired concrete samples were conducted by scanning electron microscopy accompanied with EDX analysis. The results indicated that despite the decrease in compressive strengths upon firing, investigated lightweight concretes can be categorized both as thermal insulators and structural materials.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes",
pages = "162-149",
number = "2",
volume = "52",
doi = "10.2298/SOS2002149T"
}
Terzić, A., Stojanović, J., Andrić, L., Miličić, L.,& Radojević, Z.. (2020). Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 52(2), 149-162.
https://doi.org/10.2298/SOS2002149T
Terzić A, Stojanović J, Andrić L, Miličić L, Radojević Z. Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes. in Science of Sintering. 2020;52(2):149-162.
doi:10.2298/SOS2002149T .
Terzić, Anja, Stojanović, Jovica, Andrić, Ljubiša, Miličić, Ljiljana, Radojević, Zagorka, "Performances of Vermiculite and Perlite Based Thermal Insulation Lightweight Concretes" in Science of Sintering, 52, no. 2 (2020):149-162,
https://doi.org/10.2298/SOS2002149T . .
4
3
5

Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash

Terzić, Anja; Pezo, Lato; Miličić, Ljiljana; Mijatović, Nevenka; Radojević, Zagorka; Radulović, Dragan; Andrić, Ljubiša

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2019)

TY  - JOUR
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Miličić, Ljiljana
AU  - Mijatović, Nevenka
AU  - Radojević, Zagorka
AU  - Radulović, Dragan
AU  - Andrić, Ljubiša
PY  - 2019
UR  - http://rims.institutims.rs/handle/123456789/374
AB  - Mineral additives are extensively applied as cement replacement materials in both construction concrete and mortar. Fly ash is one of the most commonly utilized additives which improve Theological properties, as well as thermal and mechanical behavior of mortar, and as such it has been widely investigated. This industrial byproduct comprises heavy metals in its composition; therefore further research is needed to optimize its effective dosage. Moreover, certain sorptive clays, such as natural zeolite and bentonite, can prevent migration of toxic elements from fly ash by immobilizing them in their structure. Ten experimental mortars are prepared with Portland cement, river sand and addition of fly ash, zeolite and/or bentonite in accordance with chemometric experimental design rules. The aim of the study was to investigate the effect of mineral additives on thermal and mechanical performances of mortar. Thermal characteristics were monitored via dilatometric analysis and DTA method. Principal component analysis was used on the results of physico-mechanical testing (workability, bulk density, water absorption, shrinkage, compressive and flexural strength) to enable the divisions of the observed samples into groups in the factor space. The performance of Artificial Neural Network was compared with the experimental data in order to develop rapid and accurate method for prediction of mechanical parameters of mortar. The ANN model showed high overall prediction accuracy (r(2) = 0.989, during training cycle). The test results indicate that incorporation of the mineral additives gave cost effective mortars with sufficiently good properties. However, tools of analytical modeling highlighted mortar with zeolite and fly ash as the optimal composition regarding its mechanical performance.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash
EP  - 56
IS  - 1
SP  - 39
VL  - 51
DO  - 10.2298/SOS1901039T
ER  - 
@article{
author = "Terzić, Anja and Pezo, Lato and Miličić, Ljiljana and Mijatović, Nevenka and Radojević, Zagorka and Radulović, Dragan and Andrić, Ljubiša",
year = "2019",
abstract = "Mineral additives are extensively applied as cement replacement materials in both construction concrete and mortar. Fly ash is one of the most commonly utilized additives which improve Theological properties, as well as thermal and mechanical behavior of mortar, and as such it has been widely investigated. This industrial byproduct comprises heavy metals in its composition; therefore further research is needed to optimize its effective dosage. Moreover, certain sorptive clays, such as natural zeolite and bentonite, can prevent migration of toxic elements from fly ash by immobilizing them in their structure. Ten experimental mortars are prepared with Portland cement, river sand and addition of fly ash, zeolite and/or bentonite in accordance with chemometric experimental design rules. The aim of the study was to investigate the effect of mineral additives on thermal and mechanical performances of mortar. Thermal characteristics were monitored via dilatometric analysis and DTA method. Principal component analysis was used on the results of physico-mechanical testing (workability, bulk density, water absorption, shrinkage, compressive and flexural strength) to enable the divisions of the observed samples into groups in the factor space. The performance of Artificial Neural Network was compared with the experimental data in order to develop rapid and accurate method for prediction of mechanical parameters of mortar. The ANN model showed high overall prediction accuracy (r(2) = 0.989, during training cycle). The test results indicate that incorporation of the mineral additives gave cost effective mortars with sufficiently good properties. However, tools of analytical modeling highlighted mortar with zeolite and fly ash as the optimal composition regarding its mechanical performance.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash",
pages = "56-39",
number = "1",
volume = "51",
doi = "10.2298/SOS1901039T"
}
Terzić, A., Pezo, L., Miličić, L., Mijatović, N., Radojević, Z., Radulović, D.,& Andrić, L.. (2019). Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(1), 39-56.
https://doi.org/10.2298/SOS1901039T
Terzić A, Pezo L, Miličić L, Mijatović N, Radojević Z, Radulović D, Andrić L. Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash. in Science of Sintering. 2019;51(1):39-56.
doi:10.2298/SOS1901039T .
Terzić, Anja, Pezo, Lato, Miličić, Ljiljana, Mijatović, Nevenka, Radojević, Zagorka, Radulović, Dragan, Andrić, Ljubiša, "Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash" in Science of Sintering, 51, no. 1 (2019):39-56,
https://doi.org/10.2298/SOS1901039T . .
3
8
9

Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition

Mijatović, Nevenka; Terzić, Anja; Pezo, Lato; Miličić, Ljiljana; Milosavljević, Aleksandra; Živojinović, Dragana

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2019)

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Miličić, Ljiljana
AU  - Milosavljević, Aleksandra
AU  - Živojinović, Dragana
PY  - 2019
UR  - http://rims.institutims.rs/handle/123456789/369
AB  - New global tendencies for waste materials reusing in building materials are imposing the request for improved performances of chemical analysis methods and the improvements of matrices used. A new method for optical emission spectrometry with inductively coupled plasma (ICP-OES) is developed and validated for the chemical analysis (35 elements: Al, Be, Cd, So, Cr, Cu, Fe, Mn, Mo, Ni, V, Mo, Zn, Pb , Bi, Si, Zr, W, As, Se, Sb, Sn, Ti, Ba, B, Ag, Mg, Ca, K, Na, S, P, Ga, In, Li) in leachate of fly ash. Validation performances and the uncertainty of measurement were resolved. Uncertainty of measurements were resolved by three routes: validation procedure, participation in proficiency testing (PT) schemes and standard method. The obtained method is a new simple and effective analyzing route for determination of undesired trace elements and their quantity comprised in leachates of fly ash, and leachates of building materials with addition of fly ash (cement binders and mortars). In order to prove its accuracy and precision, the developed method was employed on laboratory samples of cement binders and mortars. Results were compared with limit values provided in the standard. Multivariate analyses, i.e. cluster analysis and principal component analysis, were applied to establish interrelations between analyzed samples, and to certify the developed ICP-OES method.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition
EP  - 444
IS  - 4
SP  - 429
VL  - 51
DO  - 10.2298/SOS1904429M
ER  - 
@article{
author = "Mijatović, Nevenka and Terzić, Anja and Pezo, Lato and Miličić, Ljiljana and Milosavljević, Aleksandra and Živojinović, Dragana",
year = "2019",
abstract = "New global tendencies for waste materials reusing in building materials are imposing the request for improved performances of chemical analysis methods and the improvements of matrices used. A new method for optical emission spectrometry with inductively coupled plasma (ICP-OES) is developed and validated for the chemical analysis (35 elements: Al, Be, Cd, So, Cr, Cu, Fe, Mn, Mo, Ni, V, Mo, Zn, Pb , Bi, Si, Zr, W, As, Se, Sb, Sn, Ti, Ba, B, Ag, Mg, Ca, K, Na, S, P, Ga, In, Li) in leachate of fly ash. Validation performances and the uncertainty of measurement were resolved. Uncertainty of measurements were resolved by three routes: validation procedure, participation in proficiency testing (PT) schemes and standard method. The obtained method is a new simple and effective analyzing route for determination of undesired trace elements and their quantity comprised in leachates of fly ash, and leachates of building materials with addition of fly ash (cement binders and mortars). In order to prove its accuracy and precision, the developed method was employed on laboratory samples of cement binders and mortars. Results were compared with limit values provided in the standard. Multivariate analyses, i.e. cluster analysis and principal component analysis, were applied to establish interrelations between analyzed samples, and to certify the developed ICP-OES method.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition",
pages = "444-429",
number = "4",
volume = "51",
doi = "10.2298/SOS1904429M"
}
Mijatović, N., Terzić, A., Pezo, L., Miličić, L., Milosavljević, A.,& Živojinović, D.. (2019). Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(4), 429-444.
https://doi.org/10.2298/SOS1904429M
Mijatović N, Terzić A, Pezo L, Miličić L, Milosavljević A, Živojinović D. Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition. in Science of Sintering. 2019;51(4):429-444.
doi:10.2298/SOS1904429M .
Mijatović, Nevenka, Terzić, Anja, Pezo, Lato, Miličić, Ljiljana, Milosavljević, Aleksandra, Živojinović, Dragana, "Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition" in Science of Sintering, 51, no. 4 (2019):429-444,
https://doi.org/10.2298/SOS1904429M . .
1
3
4

Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites

Mijatović, Nevenka; Terzić, Anja; Pezo, Lato; Miličić, Ljiljana; Živojinović, Dragana

(Pergamon-Elsevier Science Ltd, Oxford, 2019)

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Miličić, Ljiljana
AU  - Živojinović, Dragana
PY  - 2019
UR  - http://rims.institutims.rs/handle/123456789/363
AB  - Adjustment and subsequent validation of energy-dispersive X-ray fluorescence (ED-XRF) method for cement based binders with addition of mineral raw materials (fly ash, zeolite and bentonite) was conducted. Eighteen chemical elements present in the material composition were analyzed: ten major elements (Si, Al, Fe, Ca, Mg, S, Na, K, Ti, P) and eight trace elements (Cr, Zn, Cu, As, Ni, Pb, Sr, Mn). Thirty-five samples of either certified reference materials or reference materials of cement, fly ash and clay were utilized during adjustment and optimization of the investigated ED-XRF procedure. The method was consecutively validated in terms of selectivity, precision, working range, linearity, accuracy, robustness, limits of detection and quantification. Thirty-two samples in total, i.e. three certified reference materials and twenty-nine reference materials, were simultaneously analyzed by ED-XRF and inductively coupled plasma optical emission spectrometry (ICP-OES). Comparison of the outputs of monitored methods showed infinitesimally small differences, as correlation coefficients were extremely good (approximate to 1), which highlighted ED-XRF as highly satiable alternative for ICP-OES for the chemical analysis of cement binders.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Spectrochimica Acta Part B-Atomic Spectroscopy
T1  - Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites
VL  - 162
DO  - 10.1016/j.sab.2019.105729
ER  - 
@article{
author = "Mijatović, Nevenka and Terzić, Anja and Pezo, Lato and Miličić, Ljiljana and Živojinović, Dragana",
year = "2019",
abstract = "Adjustment and subsequent validation of energy-dispersive X-ray fluorescence (ED-XRF) method for cement based binders with addition of mineral raw materials (fly ash, zeolite and bentonite) was conducted. Eighteen chemical elements present in the material composition were analyzed: ten major elements (Si, Al, Fe, Ca, Mg, S, Na, K, Ti, P) and eight trace elements (Cr, Zn, Cu, As, Ni, Pb, Sr, Mn). Thirty-five samples of either certified reference materials or reference materials of cement, fly ash and clay were utilized during adjustment and optimization of the investigated ED-XRF procedure. The method was consecutively validated in terms of selectivity, precision, working range, linearity, accuracy, robustness, limits of detection and quantification. Thirty-two samples in total, i.e. three certified reference materials and twenty-nine reference materials, were simultaneously analyzed by ED-XRF and inductively coupled plasma optical emission spectrometry (ICP-OES). Comparison of the outputs of monitored methods showed infinitesimally small differences, as correlation coefficients were extremely good (approximate to 1), which highlighted ED-XRF as highly satiable alternative for ICP-OES for the chemical analysis of cement binders.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Spectrochimica Acta Part B-Atomic Spectroscopy",
title = "Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites",
volume = "162",
doi = "10.1016/j.sab.2019.105729"
}
Mijatović, N., Terzić, A., Pezo, L., Miličić, L.,& Živojinović, D.. (2019). Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites. in Spectrochimica Acta Part B-Atomic Spectroscopy
Pergamon-Elsevier Science Ltd, Oxford., 162.
https://doi.org/10.1016/j.sab.2019.105729
Mijatović N, Terzić A, Pezo L, Miličić L, Živojinović D. Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites. in Spectrochimica Acta Part B-Atomic Spectroscopy. 2019;162.
doi:10.1016/j.sab.2019.105729 .
Mijatović, Nevenka, Terzić, Anja, Pezo, Lato, Miličić, Ljiljana, Živojinović, Dragana, "Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites" in Spectrochimica Acta Part B-Atomic Spectroscopy, 162 (2019),
https://doi.org/10.1016/j.sab.2019.105729 . .
7
3
6

Evidence of continuous pottery production during the late Byzantine period in the Studenica Monastery, a UNESCO World Heritage Site

Stojanović, Srna; Bikić, Vesna; Miličić, Ljiljana; Radosavljević-Evans, Ivana; Scarlett, Nicola V. Y.; Brand, Helen E. A.; Damjanović-Vasilić, Ljiljana

(Elsevier Science Bv, Amsterdam, 2019)

TY  - JOUR
AU  - Stojanović, Srna
AU  - Bikić, Vesna
AU  - Miličić, Ljiljana
AU  - Radosavljević-Evans, Ivana
AU  - Scarlett, Nicola V. Y.
AU  - Brand, Helen E. A.
AU  - Damjanović-Vasilić, Ljiljana
PY  - 2019
UR  - http://rims.institutims.rs/handle/123456789/371
AB  - A collection of 63 pottery shards excavated at the Studenica Monastery, Serbia, originating from two distinct cultural strata (late 12th until the late 13th century, and the 14th and the first half of 15th century) was subject of this work. Mineralogical and chemical composition of body and glaze and production technology of investigated pottery were determined combining optical microscopy, inductively coupled plasma-optical emission and wavelength dispersive X-ray fluorescence spectrometry, Fourier transform infrared and micro-Raman spectroscopy, high-resolution synchrotron powder X-ray diffraction and multivariate statistical analysis. In addition, clay rod with traces of glaze from the kiln found within the Monastery complex was investigated. The firing temperature was estimated at 600-700 degrees C for the most of cookware and at 800-1000 degrees C for tableware. Pottery, made of non-calcareous clay, was covered with transparent lead based glaze and copper and iron were used as colorants. Combining results of all used techniques no significant differences in mineralogical and chemical composition among samples from two cultural strata were identified indicating continuous pottery production process from 13th until 15th century in Studenica.
PB  - Elsevier Science Bv, Amsterdam
T2  - Microchemical Journal
T1  - Evidence of continuous pottery production during the late Byzantine period in the Studenica Monastery, a UNESCO World Heritage Site
EP  - 567
SP  - 557
VL  - 146
DO  - 10.1016/j.microc.2019.01.056
ER  - 
@article{
author = "Stojanović, Srna and Bikić, Vesna and Miličić, Ljiljana and Radosavljević-Evans, Ivana and Scarlett, Nicola V. Y. and Brand, Helen E. A. and Damjanović-Vasilić, Ljiljana",
year = "2019",
abstract = "A collection of 63 pottery shards excavated at the Studenica Monastery, Serbia, originating from two distinct cultural strata (late 12th until the late 13th century, and the 14th and the first half of 15th century) was subject of this work. Mineralogical and chemical composition of body and glaze and production technology of investigated pottery were determined combining optical microscopy, inductively coupled plasma-optical emission and wavelength dispersive X-ray fluorescence spectrometry, Fourier transform infrared and micro-Raman spectroscopy, high-resolution synchrotron powder X-ray diffraction and multivariate statistical analysis. In addition, clay rod with traces of glaze from the kiln found within the Monastery complex was investigated. The firing temperature was estimated at 600-700 degrees C for the most of cookware and at 800-1000 degrees C for tableware. Pottery, made of non-calcareous clay, was covered with transparent lead based glaze and copper and iron were used as colorants. Combining results of all used techniques no significant differences in mineralogical and chemical composition among samples from two cultural strata were identified indicating continuous pottery production process from 13th until 15th century in Studenica.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Microchemical Journal",
title = "Evidence of continuous pottery production during the late Byzantine period in the Studenica Monastery, a UNESCO World Heritage Site",
pages = "567-557",
volume = "146",
doi = "10.1016/j.microc.2019.01.056"
}
Stojanović, S., Bikić, V., Miličić, L., Radosavljević-Evans, I., Scarlett, N. V. Y., Brand, H. E. A.,& Damjanović-Vasilić, L.. (2019). Evidence of continuous pottery production during the late Byzantine period in the Studenica Monastery, a UNESCO World Heritage Site. in Microchemical Journal
Elsevier Science Bv, Amsterdam., 146, 557-567.
https://doi.org/10.1016/j.microc.2019.01.056
Stojanović S, Bikić V, Miličić L, Radosavljević-Evans I, Scarlett NVY, Brand HEA, Damjanović-Vasilić L. Evidence of continuous pottery production during the late Byzantine period in the Studenica Monastery, a UNESCO World Heritage Site. in Microchemical Journal. 2019;146:557-567.
doi:10.1016/j.microc.2019.01.056 .
Stojanović, Srna, Bikić, Vesna, Miličić, Ljiljana, Radosavljević-Evans, Ivana, Scarlett, Nicola V. Y., Brand, Helen E. A., Damjanović-Vasilić, Ljiljana, "Evidence of continuous pottery production during the late Byzantine period in the Studenica Monastery, a UNESCO World Heritage Site" in Microchemical Journal, 146 (2019):557-567,
https://doi.org/10.1016/j.microc.2019.01.056 . .
3
2
2

Svojstva i performanse maltera sa dodatkom primarnih i sekundarnih mineralnih sirovina u cilju zamene cementnog veziva

Terzić, Anja; Mijatović, Nevenka; Miličić, Ljiljana; Radojević, Zagorka

(Savez inženjera i tehničara Srbije, Beograd, 2018)

TY  - JOUR
AU  - Terzić, Anja
AU  - Mijatović, Nevenka
AU  - Miličić, Ljiljana
AU  - Radojević, Zagorka
PY  - 2018
UR  - http://rims.institutims.rs/handle/123456789/348
AB  - Mineralni dodaci se ekstenzivno koriste kao zamena za cement u građevinskim betonima i malterima. Leteći pepeo je jedan od najčešće primenjivanih dodataka koji unapređuje reološka, mehanička i termička svojstva materijala. Međutim, ovaj industrijski nusprodukat sadrži teške metale zbog čega je neophodna optimizacija njegove dozaže pri dizajnu maltera. Glineni materiali kao što su zeolit i bentonit svojim sorpcionim mehanizmima mogu da preduprede migraciju toksičnih elemenata iz pepela imobilišući ih unutar strukture. U ovom radu eksperimentalno su ispitana tri različita maltera pripremljena na bazi Portland cementa, rečnog peska i kombinacije mineralnih dodataka - letećeg pepela, zeolita i bentonita. Malter M1 sadržao je sva tri dodatka u odnosu 1:1:1, malter M2 je sadržao zeolit i bentonit u odnosu 1:2, dok je odnos zeolita i bentonita u malteru M3 bio 2:1. Cilj istraživanja je bio da se ispita uticaj mineralnih dodataka na fizičko-hemijska, termička i mehanička svojstva maltera. Primenjene su instrumentalne metode - X-ray difrakcija, diferencijalno termijska i dilatometrijska analiza i FTIR spektroskopija. Rezultati istraživanja su ukazali da se primenom ovih mineralnih dodataka mogu dobiti ekonomični malteri sa dovoljno dobrim performansama.
AB  - Mineral additives are extensively applied as cement replacements in building concretes and mortars. Fly ash is one of the most commonly used additives which enhance rheological, mechanical and thermal properties of material. However, this industrial byproduct comprises heavy metals; therefore the optimization of its effective dosage is necessary. Clayey materials, such as zeolite and bentonite, can prevent migration of toxic elements from fly ash by immobilizing them in their structure. In this paper, three experimental mortars where designed, prepared and investigated. Mortars were based on Portland cement, river sand and mineral additive - fly ash, zeolite and bentonite. Mortar M1 comprised all three additives used in 1:1:1 ratio, mortar M2 contained zeolite and bentonite in 1:2 ratio, while ratio of zeolite and bentonite in M3 mortar was 2:1. The aim of the study was to investigate the effect of mineral additives on physico-chemical, thermal and mechanical performances of mortar. X-ray diffraction, DTA, dilatometry and FRIR analyses were applied on mortar samples. The results of the investigation highlighted that economical mortar with good properties can be obtained by application of these mineral additives.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Svojstva i performanse maltera sa dodatkom primarnih i sekundarnih mineralnih sirovina u cilju zamene cementnog veziva
T1  - Properties and performances of mortars with primary and secondary mineral additives applied as cement replacement
EP  - 476
IS  - 4
SP  - 470
VL  - 73
DO  - 10.5937/tehnika1804470T
ER  - 
@article{
author = "Terzić, Anja and Mijatović, Nevenka and Miličić, Ljiljana and Radojević, Zagorka",
year = "2018",
abstract = "Mineralni dodaci se ekstenzivno koriste kao zamena za cement u građevinskim betonima i malterima. Leteći pepeo je jedan od najčešće primenjivanih dodataka koji unapređuje reološka, mehanička i termička svojstva materijala. Međutim, ovaj industrijski nusprodukat sadrži teške metale zbog čega je neophodna optimizacija njegove dozaže pri dizajnu maltera. Glineni materiali kao što su zeolit i bentonit svojim sorpcionim mehanizmima mogu da preduprede migraciju toksičnih elemenata iz pepela imobilišući ih unutar strukture. U ovom radu eksperimentalno su ispitana tri različita maltera pripremljena na bazi Portland cementa, rečnog peska i kombinacije mineralnih dodataka - letećeg pepela, zeolita i bentonita. Malter M1 sadržao je sva tri dodatka u odnosu 1:1:1, malter M2 je sadržao zeolit i bentonit u odnosu 1:2, dok je odnos zeolita i bentonita u malteru M3 bio 2:1. Cilj istraživanja je bio da se ispita uticaj mineralnih dodataka na fizičko-hemijska, termička i mehanička svojstva maltera. Primenjene su instrumentalne metode - X-ray difrakcija, diferencijalno termijska i dilatometrijska analiza i FTIR spektroskopija. Rezultati istraživanja su ukazali da se primenom ovih mineralnih dodataka mogu dobiti ekonomični malteri sa dovoljno dobrim performansama., Mineral additives are extensively applied as cement replacements in building concretes and mortars. Fly ash is one of the most commonly used additives which enhance rheological, mechanical and thermal properties of material. However, this industrial byproduct comprises heavy metals; therefore the optimization of its effective dosage is necessary. Clayey materials, such as zeolite and bentonite, can prevent migration of toxic elements from fly ash by immobilizing them in their structure. In this paper, three experimental mortars where designed, prepared and investigated. Mortars were based on Portland cement, river sand and mineral additive - fly ash, zeolite and bentonite. Mortar M1 comprised all three additives used in 1:1:1 ratio, mortar M2 contained zeolite and bentonite in 1:2 ratio, while ratio of zeolite and bentonite in M3 mortar was 2:1. The aim of the study was to investigate the effect of mineral additives on physico-chemical, thermal and mechanical performances of mortar. X-ray diffraction, DTA, dilatometry and FRIR analyses were applied on mortar samples. The results of the investigation highlighted that economical mortar with good properties can be obtained by application of these mineral additives.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Svojstva i performanse maltera sa dodatkom primarnih i sekundarnih mineralnih sirovina u cilju zamene cementnog veziva, Properties and performances of mortars with primary and secondary mineral additives applied as cement replacement",
pages = "476-470",
number = "4",
volume = "73",
doi = "10.5937/tehnika1804470T"
}
Terzić, A., Mijatović, N., Miličić, L.,& Radojević, Z.. (2018). Svojstva i performanse maltera sa dodatkom primarnih i sekundarnih mineralnih sirovina u cilju zamene cementnog veziva. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 73(4), 470-476.
https://doi.org/10.5937/tehnika1804470T
Terzić A, Mijatović N, Miličić L, Radojević Z. Svojstva i performanse maltera sa dodatkom primarnih i sekundarnih mineralnih sirovina u cilju zamene cementnog veziva. in Tehnika. 2018;73(4):470-476.
doi:10.5937/tehnika1804470T .
Terzić, Anja, Mijatović, Nevenka, Miličić, Ljiljana, Radojević, Zagorka, "Svojstva i performanse maltera sa dodatkom primarnih i sekundarnih mineralnih sirovina u cilju zamene cementnog veziva" in Tehnika, 73, no. 4 (2018):470-476,
https://doi.org/10.5937/tehnika1804470T . .

The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders

Terzić, Anja; Pezo, Lato; Mijatović, Nevenka; Stojanović, Jovica; Kragović, Milan; Miličić, Ljiljana; Andrić, Ljubiša

(Elsevier Sci Ltd, Oxford, 2018)

TY  - JOUR
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Mijatović, Nevenka
AU  - Stojanović, Jovica
AU  - Kragović, Milan
AU  - Miličić, Ljiljana
AU  - Andrić, Ljubiša
PY  - 2018
UR  - http://rims.institutims.rs/handle/123456789/345
AB  - Instrumental analyses accompanied by analytical modeling tools were employed to assess physico-chemical changes induced by variations in chemical composition of cementitious composites, i.e. mortar binders. Coal combustion ash was utilized as pozzolanic mineral additive. The binders' mix-design was supplemented with sorptive clays to prevent migration of toxic elements from fly ash. The experiment was established on the premise of clay's ion-exchanging ability. Ten binders comprising cement CEM I 42.5 and fly ash, zeolite and/or bentonite additions were prepared in accordance with chemometric experimental design rules. Chemical composition was determined via XRF method. The changes in mineral phases and crystallinity were traced by X-ray diffraction. Hydration mechanisms and thermal behavior were investigated via DTA/TGA. The chemical bonds were identified by FTIR. Morphology of hardened samples was detected by SEM. Mathematical tools employed data sets of instrumental analyses to form a clear differentiation between binders and to assess changes caused by adoption of mineral additives in the mix designs. Sorptive clays showed pozzolanic behavior, thereby causing no incapacitation to the cement hydration mechanism, and classifying as a possible economical resources which can be used in production technology of construction materials to redeem environmental pollution issues of building industry.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders
EP  - 210
SP  - 199
VL  - 180
DO  - 10.1016/j.conbuildmat.2018.06.007
ER  - 
@article{
author = "Terzić, Anja and Pezo, Lato and Mijatović, Nevenka and Stojanović, Jovica and Kragović, Milan and Miličić, Ljiljana and Andrić, Ljubiša",
year = "2018",
abstract = "Instrumental analyses accompanied by analytical modeling tools were employed to assess physico-chemical changes induced by variations in chemical composition of cementitious composites, i.e. mortar binders. Coal combustion ash was utilized as pozzolanic mineral additive. The binders' mix-design was supplemented with sorptive clays to prevent migration of toxic elements from fly ash. The experiment was established on the premise of clay's ion-exchanging ability. Ten binders comprising cement CEM I 42.5 and fly ash, zeolite and/or bentonite additions were prepared in accordance with chemometric experimental design rules. Chemical composition was determined via XRF method. The changes in mineral phases and crystallinity were traced by X-ray diffraction. Hydration mechanisms and thermal behavior were investigated via DTA/TGA. The chemical bonds were identified by FTIR. Morphology of hardened samples was detected by SEM. Mathematical tools employed data sets of instrumental analyses to form a clear differentiation between binders and to assess changes caused by adoption of mineral additives in the mix designs. Sorptive clays showed pozzolanic behavior, thereby causing no incapacitation to the cement hydration mechanism, and classifying as a possible economical resources which can be used in production technology of construction materials to redeem environmental pollution issues of building industry.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders",
pages = "210-199",
volume = "180",
doi = "10.1016/j.conbuildmat.2018.06.007"
}
Terzić, A., Pezo, L., Mijatović, N., Stojanović, J., Kragović, M., Miličić, L.,& Andrić, L.. (2018). The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 180, 199-210.
https://doi.org/10.1016/j.conbuildmat.2018.06.007
Terzić A, Pezo L, Mijatović N, Stojanović J, Kragović M, Miličić L, Andrić L. The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders. in Construction and Building Materials. 2018;180:199-210.
doi:10.1016/j.conbuildmat.2018.06.007 .
Terzić, Anja, Pezo, Lato, Mijatović, Nevenka, Stojanović, Jovica, Kragović, Milan, Miličić, Ljiljana, Andrić, Ljubiša, "The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders" in Construction and Building Materials, 180 (2018):199-210,
https://doi.org/10.1016/j.conbuildmat.2018.06.007 . .
28
22
30

Compressive strength and microstructure of ordinary cured and autoclaved cement-based composites with mechanically activated kaolins

Ilić, Biljana; Mitrović, Aleksandra; Miličić, Ljiljana; Zdujić, Miodrag

(Elsevier Sci Ltd, Oxford, 2018)

TY  - JOUR
AU  - Ilić, Biljana
AU  - Mitrović, Aleksandra
AU  - Miličić, Ljiljana
AU  - Zdujić, Miodrag
PY  - 2018
UR  - http://rims.institutims.rs/handle/123456789/347
AB  - The effects of two different mechanically activated kaolins, AKV (61% kaolinite, 14% quartz and 16% mica) and AKG (51.6% kaolinite and 40.6% quartz) on the compressive strength of cement composites and microstructure of pastes were investigated. Composite mixtures, in which 10, 20, 30, 40 and 50% of ordinary Portland cement (OPC) was replaced by AKV or AKG, were prepared with w/b of 0.5, and exposed to different curing conditions (ordinary curing for 28 days and autoclaving). Factors affecting microstructure were investigated on pastes by X-ray diffraction (XRD), Differential thermal analysis/thermal gravimetry (DTA/TG) analyses. Mercury intrusion porosimetry (MIP) and Scanning electron microscopy with Energy-dispersive spectroscopy (SEM-EDS). AKG composites exhibited higher compressive strengths under both curing conditions. Positive autoclaving effects on strengths were predominantly pronounced at the higher cement replacement levels. Comparison of the autoclaved and ordinary cured paste microstructure, revealed more intensive pozzolanic reaction during autoclaving conditions (CH content near zero) and higher total porosity. The negative effect of hydrogarnet on the strength was compensated by the formation of the crystalline tobermorite. Obtained results revealed that mechanically activated kaolin, with high content of quartz, could be a promising pozzolanic addition, even at high cement replacement levels (30-50%), especially when autoclaving curing conditions were applied.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - Compressive strength and microstructure of ordinary cured and autoclaved cement-based composites with mechanically activated kaolins
EP  - 101
SP  - 92
VL  - 178
DO  - 10.1016/j.conbuildmat.2018.05.144
ER  - 
@article{
author = "Ilić, Biljana and Mitrović, Aleksandra and Miličić, Ljiljana and Zdujić, Miodrag",
year = "2018",
abstract = "The effects of two different mechanically activated kaolins, AKV (61% kaolinite, 14% quartz and 16% mica) and AKG (51.6% kaolinite and 40.6% quartz) on the compressive strength of cement composites and microstructure of pastes were investigated. Composite mixtures, in which 10, 20, 30, 40 and 50% of ordinary Portland cement (OPC) was replaced by AKV or AKG, were prepared with w/b of 0.5, and exposed to different curing conditions (ordinary curing for 28 days and autoclaving). Factors affecting microstructure were investigated on pastes by X-ray diffraction (XRD), Differential thermal analysis/thermal gravimetry (DTA/TG) analyses. Mercury intrusion porosimetry (MIP) and Scanning electron microscopy with Energy-dispersive spectroscopy (SEM-EDS). AKG composites exhibited higher compressive strengths under both curing conditions. Positive autoclaving effects on strengths were predominantly pronounced at the higher cement replacement levels. Comparison of the autoclaved and ordinary cured paste microstructure, revealed more intensive pozzolanic reaction during autoclaving conditions (CH content near zero) and higher total porosity. The negative effect of hydrogarnet on the strength was compensated by the formation of the crystalline tobermorite. Obtained results revealed that mechanically activated kaolin, with high content of quartz, could be a promising pozzolanic addition, even at high cement replacement levels (30-50%), especially when autoclaving curing conditions were applied.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "Compressive strength and microstructure of ordinary cured and autoclaved cement-based composites with mechanically activated kaolins",
pages = "101-92",
volume = "178",
doi = "10.1016/j.conbuildmat.2018.05.144"
}
Ilić, B., Mitrović, A., Miličić, L.,& Zdujić, M.. (2018). Compressive strength and microstructure of ordinary cured and autoclaved cement-based composites with mechanically activated kaolins. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 178, 92-101.
https://doi.org/10.1016/j.conbuildmat.2018.05.144
Ilić B, Mitrović A, Miličić L, Zdujić M. Compressive strength and microstructure of ordinary cured and autoclaved cement-based composites with mechanically activated kaolins. in Construction and Building Materials. 2018;178:92-101.
doi:10.1016/j.conbuildmat.2018.05.144 .
Ilić, Biljana, Mitrović, Aleksandra, Miličić, Ljiljana, Zdujić, Miodrag, "Compressive strength and microstructure of ordinary cured and autoclaved cement-based composites with mechanically activated kaolins" in Construction and Building Materials, 178 (2018):92-101,
https://doi.org/10.1016/j.conbuildmat.2018.05.144 . .
16
6
18

The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites

Terzić, Anja; Radulović, Dragan; Pezo, Lato; Andrić, Ljubiša; Miličić, Ljiljana; Stojanović, Jovica; Grigorova, Irena

(Elsevier Sci Ltd, Oxford, 2017)

TY  - JOUR
AU  - Terzić, Anja
AU  - Radulović, Dragan
AU  - Pezo, Lato
AU  - Andrić, Ljubiša
AU  - Miličić, Ljiljana
AU  - Stojanović, Jovica
AU  - Grigorova, Irena
PY  - 2017
UR  - http://rims.institutims.rs/handle/123456789/322
AB  - The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.
PB  - Elsevier Sci Ltd, Oxford
T2  - Composites Part B-Engineering
T1  - The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites
EP  - 73
SP  - 61
VL  - 117
DO  - 10.1016/j.compositesb.2017.02.041
ER  - 
@article{
author = "Terzić, Anja and Radulović, Dragan and Pezo, Lato and Andrić, Ljubiša and Miličić, Ljiljana and Stojanović, Jovica and Grigorova, Irena",
year = "2017",
abstract = "The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Composites Part B-Engineering",
title = "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites",
pages = "73-61",
volume = "117",
doi = "10.1016/j.compositesb.2017.02.041"
}
Terzić, A., Radulović, D., Pezo, L., Andrić, L., Miličić, L., Stojanović, J.,& Grigorova, I.. (2017). The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering
Elsevier Sci Ltd, Oxford., 117, 61-73.
https://doi.org/10.1016/j.compositesb.2017.02.041
Terzić A, Radulović D, Pezo L, Andrić L, Miličić L, Stojanović J, Grigorova I. The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering. 2017;117:61-73.
doi:10.1016/j.compositesb.2017.02.041 .
Terzić, Anja, Radulović, Dragan, Pezo, Lato, Andrić, Ljubiša, Miličić, Ljiljana, Stojanović, Jovica, Grigorova, Irena, "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites" in Composites Part B-Engineering, 117 (2017):61-73,
https://doi.org/10.1016/j.compositesb.2017.02.041 . .
10
9
10

The geochemistry model of the surface sediment determined by using ED-XRF technique: a case study of the Boka Kotorska bay, Adriatic Sea

Tanaskovski, Bojan; Jović, Mihajlo; Miličić, Ljiljana; Pezo, Lato; Mandić, Milica; Stanković, Slavka

(Springer Heidelberg, Heidelberg, 2016)

TY  - JOUR
AU  - Tanaskovski, Bojan
AU  - Jović, Mihajlo
AU  - Miličić, Ljiljana
AU  - Pezo, Lato
AU  - Mandić, Milica
AU  - Stanković, Slavka
PY  - 2016
UR  - http://rims.institutims.rs/handle/123456789/293
AB  - The spatial distribution of major oxides (Na2O, K2O, SiO2, Al2O3, Fe2O3, CaO, MgO, MnO, TiO2, P2O5) and numerous elements (Cr, Co, Ni, Cu, Zn, As, Se, Pb, Sn, Sb, Ba, Sr, Br, Rb, Zr, Mo, Cs, Y, V, Ga, La, U, Th, Nb, W, Sc, Ge, Gd, Yb, Hf, and Ce) was determined by using energy dispersive X-ray fluorescence spectrometry on the basis of previously measured organic matter and carbonates. The optimal measuring variables for the investigated oxides and elements were determined by using five standard reference materials. The carbonated sediment type can be determined on the basis of the highest Sr, Sc, La, Nb, Hf, and Yb concentrations followed with the lowest concentrations of the remaining elements and the negative Ce anomaly. The complexity of the obtained data was also examined by principal component analysis (PCA) and cluster analysis (CA) in the identifying geochemical composition of the surface sediment. Boka Kotorska bay's geographical position, orographical configuration, and hydrographic characteristics influence the geochemistry model of the surface sediment, quite different from the open sea.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - The geochemistry model of the surface sediment determined by using ED-XRF technique: a case study of the Boka Kotorska bay, Adriatic Sea
EP  - 11789
IS  - 12
SP  - 11777
VL  - 23
DO  - 10.1007/s11356-016-6353-6
ER  - 
@article{
author = "Tanaskovski, Bojan and Jović, Mihajlo and Miličić, Ljiljana and Pezo, Lato and Mandić, Milica and Stanković, Slavka",
year = "2016",
abstract = "The spatial distribution of major oxides (Na2O, K2O, SiO2, Al2O3, Fe2O3, CaO, MgO, MnO, TiO2, P2O5) and numerous elements (Cr, Co, Ni, Cu, Zn, As, Se, Pb, Sn, Sb, Ba, Sr, Br, Rb, Zr, Mo, Cs, Y, V, Ga, La, U, Th, Nb, W, Sc, Ge, Gd, Yb, Hf, and Ce) was determined by using energy dispersive X-ray fluorescence spectrometry on the basis of previously measured organic matter and carbonates. The optimal measuring variables for the investigated oxides and elements were determined by using five standard reference materials. The carbonated sediment type can be determined on the basis of the highest Sr, Sc, La, Nb, Hf, and Yb concentrations followed with the lowest concentrations of the remaining elements and the negative Ce anomaly. The complexity of the obtained data was also examined by principal component analysis (PCA) and cluster analysis (CA) in the identifying geochemical composition of the surface sediment. Boka Kotorska bay's geographical position, orographical configuration, and hydrographic characteristics influence the geochemistry model of the surface sediment, quite different from the open sea.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "The geochemistry model of the surface sediment determined by using ED-XRF technique: a case study of the Boka Kotorska bay, Adriatic Sea",
pages = "11789-11777",
number = "12",
volume = "23",
doi = "10.1007/s11356-016-6353-6"
}
Tanaskovski, B., Jović, M., Miličić, L., Pezo, L., Mandić, M.,& Stanković, S.. (2016). The geochemistry model of the surface sediment determined by using ED-XRF technique: a case study of the Boka Kotorska bay, Adriatic Sea. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 23(12), 11777-11789.
https://doi.org/10.1007/s11356-016-6353-6
Tanaskovski B, Jović M, Miličić L, Pezo L, Mandić M, Stanković S. The geochemistry model of the surface sediment determined by using ED-XRF technique: a case study of the Boka Kotorska bay, Adriatic Sea. in Environmental Science and Pollution Research. 2016;23(12):11777-11789.
doi:10.1007/s11356-016-6353-6 .
Tanaskovski, Bojan, Jović, Mihajlo, Miličić, Ljiljana, Pezo, Lato, Mandić, Milica, Stanković, Slavka, "The geochemistry model of the surface sediment determined by using ED-XRF technique: a case study of the Boka Kotorska bay, Adriatic Sea" in Environmental Science and Pollution Research, 23, no. 12 (2016):11777-11789,
https://doi.org/10.1007/s11356-016-6353-6 . .
7
4
7

Energy transfer and conversion recorded on mechanically activated fly ash grains

Terzić, Anja; Andrić, Ljubiša; Miličić, Ljiljana; Radojević, Zagorka

(ModTech Publishing House, 2015)

TY  - JOUR
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
AU  - Miličić, Ljiljana
AU  - Radojević, Zagorka
PY  - 2015
UR  - http://rims.institutims.rs/handle/123456789/263
AB  - The fly ash activation through mechanical milling is ussualy applied to improve the ash properties in order to get composite materials with higher characteristics. The activation technology based on mechanical energy action applied on treated materials and is conducted by ultra-fine milling. In order to increase the reactivity of lignite coal fly ash this paper focuses on optimization of mechanical activation period. Also, the influence of the ash activation parameters on the grain-size distribution related characteristics was studied during this research. The ash grain inertia measurement through automatic grain counter (AGC) was performed. Due this mechanically activated grains are the most convenient mineral form for measurement of grain inertia since energy change that occurs in the mill material system is recorded by them. The ash grains energy and properties could be changed by mechanical forces. The ash was thoroughly analyzed, particularly in its activated state, primarily by means of the X-ray diffraction method for a reliable identification of the crystal phases and changes in the crystallinity, followed by comparison of the SEM microphotographs of its initial and activated state.
PB  - ModTech Publishing House
T2  - International Journal of Modern Manufacturing Technologies
T1  - Energy transfer and conversion recorded on mechanically activated fly ash grains
EP  - 80
IS  - 1
SP  - 75
VL  - 7
UR  - https://hdl.handle.net/21.15107/rcub_rims_263
ER  - 
@article{
author = "Terzić, Anja and Andrić, Ljubiša and Miličić, Ljiljana and Radojević, Zagorka",
year = "2015",
abstract = "The fly ash activation through mechanical milling is ussualy applied to improve the ash properties in order to get composite materials with higher characteristics. The activation technology based on mechanical energy action applied on treated materials and is conducted by ultra-fine milling. In order to increase the reactivity of lignite coal fly ash this paper focuses on optimization of mechanical activation period. Also, the influence of the ash activation parameters on the grain-size distribution related characteristics was studied during this research. The ash grain inertia measurement through automatic grain counter (AGC) was performed. Due this mechanically activated grains are the most convenient mineral form for measurement of grain inertia since energy change that occurs in the mill material system is recorded by them. The ash grains energy and properties could be changed by mechanical forces. The ash was thoroughly analyzed, particularly in its activated state, primarily by means of the X-ray diffraction method for a reliable identification of the crystal phases and changes in the crystallinity, followed by comparison of the SEM microphotographs of its initial and activated state.",
publisher = "ModTech Publishing House",
journal = "International Journal of Modern Manufacturing Technologies",
title = "Energy transfer and conversion recorded on mechanically activated fly ash grains",
pages = "80-75",
number = "1",
volume = "7",
url = "https://hdl.handle.net/21.15107/rcub_rims_263"
}
Terzić, A., Andrić, L., Miličić, L.,& Radojević, Z.. (2015). Energy transfer and conversion recorded on mechanically activated fly ash grains. in International Journal of Modern Manufacturing Technologies
ModTech Publishing House., 7(1), 75-80.
https://hdl.handle.net/21.15107/rcub_rims_263
Terzić A, Andrić L, Miličić L, Radojević Z. Energy transfer and conversion recorded on mechanically activated fly ash grains. in International Journal of Modern Manufacturing Technologies. 2015;7(1):75-80.
https://hdl.handle.net/21.15107/rcub_rims_263 .
Terzić, Anja, Andrić, Ljubiša, Miličić, Ljiljana, Radojević, Zagorka, "Energy transfer and conversion recorded on mechanically activated fly ash grains" in International Journal of Modern Manufacturing Technologies, 7, no. 1 (2015):75-80,
https://hdl.handle.net/21.15107/rcub_rims_263 .

Investigation of the mortar and concrete resistance in aggressive solutions

Janković, Ksenija; Miličić, Ljiljana; Stanković, Srboljub J.; Šušić, Nenad

(Univ Osijek, Tech Fac, Slavonski Brod, 2014)

TY  - JOUR
AU  - Janković, Ksenija
AU  - Miličić, Ljiljana
AU  - Stanković, Srboljub J.
AU  - Šušić, Nenad
PY  - 2014
UR  - http://rims.institutims.rs/handle/123456789/227
AB  - Testing the influence of two aggressive solutions - sulphate and nitrate on mortar and concrete was presented in this paper. Experimental work included testing of mortar prisms with 5 % special admixture. Also, four types of concrete were exposed to aggressive solutions. The chemical resistance was tested according to the Koch-Steinegger method. As a condition for resistance in aggressive solution means that flexural strength of mortar prisms is no less than 70 % of referent prisms cured in water it can be concluded that mortar and concrete made with combination of cement and admixture presented in this investigation are not resistant to ammonium nitrate solution, but are resistant to sulphate corrosion.
PB  - Univ Osijek, Tech Fac, Slavonski Brod
T2  - Tehnicki Vjesnik-Technical Gazette
T1  - Investigation of the mortar and concrete resistance in aggressive solutions
EP  - 176
IS  - 1
SP  - 173
VL  - 21
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5903
ER  - 
@article{
author = "Janković, Ksenija and Miličić, Ljiljana and Stanković, Srboljub J. and Šušić, Nenad",
year = "2014",
abstract = "Testing the influence of two aggressive solutions - sulphate and nitrate on mortar and concrete was presented in this paper. Experimental work included testing of mortar prisms with 5 % special admixture. Also, four types of concrete were exposed to aggressive solutions. The chemical resistance was tested according to the Koch-Steinegger method. As a condition for resistance in aggressive solution means that flexural strength of mortar prisms is no less than 70 % of referent prisms cured in water it can be concluded that mortar and concrete made with combination of cement and admixture presented in this investigation are not resistant to ammonium nitrate solution, but are resistant to sulphate corrosion.",
publisher = "Univ Osijek, Tech Fac, Slavonski Brod",
journal = "Tehnicki Vjesnik-Technical Gazette",
title = "Investigation of the mortar and concrete resistance in aggressive solutions",
pages = "176-173",
number = "1",
volume = "21",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5903"
}
Janković, K., Miličić, L., Stanković, S. J.,& Šušić, N.. (2014). Investigation of the mortar and concrete resistance in aggressive solutions. in Tehnicki Vjesnik-Technical Gazette
Univ Osijek, Tech Fac, Slavonski Brod., 21(1), 173-176.
https://hdl.handle.net/21.15107/rcub_vinar_5903
Janković K, Miličić L, Stanković SJ, Šušić N. Investigation of the mortar and concrete resistance in aggressive solutions. in Tehnicki Vjesnik-Technical Gazette. 2014;21(1):173-176.
https://hdl.handle.net/21.15107/rcub_vinar_5903 .
Janković, Ksenija, Miličić, Ljiljana, Stanković, Srboljub J., Šušić, Nenad, "Investigation of the mortar and concrete resistance in aggressive solutions" in Tehnicki Vjesnik-Technical Gazette, 21, no. 1 (2014):173-176,
https://hdl.handle.net/21.15107/rcub_vinar_5903 .
4
4

Investigation of high temperature behavior and sintering mechanism of fly ash based concretes

Terzić, Anja; Andrić, Ljubiša; Petrov, Milan; Radojević, Zagorka; Miličić, Ljiljana

(Procema SA, 2014)

TY  - JOUR
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
AU  - Petrov, Milan
AU  - Radojević, Zagorka
AU  - Miličić, Ljiljana
PY  - 2014
UR  - http://rims.institutims.rs/handle/123456789/259
AB  - Four types of refractory concretes were studied at various temperatures ranging from ambient to adopted maximal 1400 degrees C. The concretes had same matrix composition: K concretes were based on corundum aggregate; B concretes were based on bauxite aggregate and chamotte filler; while K2 and B2 concretes had 30 % of fly ash replacement in bonding agent. Fly ash was mechanically activated by means of planetary ball mill. Samples were dried at 110 degrees C during 24 hours to create standard specimens. Afterwards, the samples were preburned at 1100 degrees C and subsequently subjected to compressive uniaxial creep test conducted at various temperatures (1200, 1300 and 1400 degrees C). Thermal behavior was also investigated by dilatometry analysis starting from room temperature up to 1400 degrees C. The evolution of the refractory concretes behavior from quasi-brittle to viscoplastic was investigated and correlated to their microstructure evolution induced by sintering process. The influence of the burning temperature and procedure duration on the concretes behavior is also discussed. Creep test and dilatometry analysis helped in defining of the sintering mechanism and its parameters, and additionally explained deformation nature of the refractory concretes.
PB  - Procema SA
T2  - Revista Romana de Materiale/ Romanian Journal of Materials
T1  - Investigation of high temperature behavior and sintering mechanism of fly ash based concretes
EP  - 224
IS  - 3
SP  - 213
VL  - 44
UR  - https://hdl.handle.net/21.15107/rcub_rims_259
ER  - 
@article{
author = "Terzić, Anja and Andrić, Ljubiša and Petrov, Milan and Radojević, Zagorka and Miličić, Ljiljana",
year = "2014",
abstract = "Four types of refractory concretes were studied at various temperatures ranging from ambient to adopted maximal 1400 degrees C. The concretes had same matrix composition: K concretes were based on corundum aggregate; B concretes were based on bauxite aggregate and chamotte filler; while K2 and B2 concretes had 30 % of fly ash replacement in bonding agent. Fly ash was mechanically activated by means of planetary ball mill. Samples were dried at 110 degrees C during 24 hours to create standard specimens. Afterwards, the samples were preburned at 1100 degrees C and subsequently subjected to compressive uniaxial creep test conducted at various temperatures (1200, 1300 and 1400 degrees C). Thermal behavior was also investigated by dilatometry analysis starting from room temperature up to 1400 degrees C. The evolution of the refractory concretes behavior from quasi-brittle to viscoplastic was investigated and correlated to their microstructure evolution induced by sintering process. The influence of the burning temperature and procedure duration on the concretes behavior is also discussed. Creep test and dilatometry analysis helped in defining of the sintering mechanism and its parameters, and additionally explained deformation nature of the refractory concretes.",
publisher = "Procema SA",
journal = "Revista Romana de Materiale/ Romanian Journal of Materials",
title = "Investigation of high temperature behavior and sintering mechanism of fly ash based concretes",
pages = "224-213",
number = "3",
volume = "44",
url = "https://hdl.handle.net/21.15107/rcub_rims_259"
}
Terzić, A., Andrić, L., Petrov, M., Radojević, Z.,& Miličić, L.. (2014). Investigation of high temperature behavior and sintering mechanism of fly ash based concretes. in Revista Romana de Materiale/ Romanian Journal of Materials
Procema SA., 44(3), 213-224.
https://hdl.handle.net/21.15107/rcub_rims_259
Terzić A, Andrić L, Petrov M, Radojević Z, Miličić L. Investigation of high temperature behavior and sintering mechanism of fly ash based concretes. in Revista Romana de Materiale/ Romanian Journal of Materials. 2014;44(3):213-224.
https://hdl.handle.net/21.15107/rcub_rims_259 .
Terzić, Anja, Andrić, Ljubiša, Petrov, Milan, Radojević, Zagorka, Miličić, Ljiljana, "Investigation of high temperature behavior and sintering mechanism of fly ash based concretes" in Revista Romana de Materiale/ Romanian Journal of Materials, 44, no. 3 (2014):213-224,
https://hdl.handle.net/21.15107/rcub_rims_259 .
2
3

Properties of composite cement with commercial and manufactured metakaolin

Mitrović, Aleksandra; Nikolić, Dragan; Miličić, Ljiljana; Bojović, Dragan

(Univ Osijek, Tech Fac, Slavonski Brod, 2013)

TY  - JOUR
AU  - Mitrović, Aleksandra
AU  - Nikolić, Dragan
AU  - Miličić, Ljiljana
AU  - Bojović, Dragan
PY  - 2013
UR  - http://rims.institutims.rs/handle/123456789/213
AB  - Metakaolin composite cements were prepared with 5 to 35 % replacement of ordinary Portland cement with metakaolin (MK), manufactured by thermal activation/calcination of domestic kaolin clay, and commercial matakaolin (CMK). Performance of the composite cements was evaluated through the setting time (initial and final), compressive strengths (for ages 2, 7, 28, 90 and 180 days) and soundness, and compared with control cement (Portland cement - CEM I). After 28 days, compressive strength was higher than that for control cement for cements prepared with addition of CMK, and with addition of up to 25 % MK.
PB  - Univ Osijek, Tech Fac, Slavonski Brod
T2  - Tehnicki Vjesnik-Technical Gazette
T1  - Properties of composite cement with commercial and manufactured metakaolin
EP  - 687
IS  - 4
SP  - 683
VL  - 20
UR  - https://hdl.handle.net/21.15107/rcub_rims_213
ER  - 
@article{
author = "Mitrović, Aleksandra and Nikolić, Dragan and Miličić, Ljiljana and Bojović, Dragan",
year = "2013",
abstract = "Metakaolin composite cements were prepared with 5 to 35 % replacement of ordinary Portland cement with metakaolin (MK), manufactured by thermal activation/calcination of domestic kaolin clay, and commercial matakaolin (CMK). Performance of the composite cements was evaluated through the setting time (initial and final), compressive strengths (for ages 2, 7, 28, 90 and 180 days) and soundness, and compared with control cement (Portland cement - CEM I). After 28 days, compressive strength was higher than that for control cement for cements prepared with addition of CMK, and with addition of up to 25 % MK.",
publisher = "Univ Osijek, Tech Fac, Slavonski Brod",
journal = "Tehnicki Vjesnik-Technical Gazette",
title = "Properties of composite cement with commercial and manufactured metakaolin",
pages = "687-683",
number = "4",
volume = "20",
url = "https://hdl.handle.net/21.15107/rcub_rims_213"
}
Mitrović, A., Nikolić, D., Miličić, L.,& Bojović, D.. (2013). Properties of composite cement with commercial and manufactured metakaolin. in Tehnicki Vjesnik-Technical Gazette
Univ Osijek, Tech Fac, Slavonski Brod., 20(4), 683-687.
https://hdl.handle.net/21.15107/rcub_rims_213
Mitrović A, Nikolić D, Miličić L, Bojović D. Properties of composite cement with commercial and manufactured metakaolin. in Tehnicki Vjesnik-Technical Gazette. 2013;20(4):683-687.
https://hdl.handle.net/21.15107/rcub_rims_213 .
Mitrović, Aleksandra, Nikolić, Dragan, Miličić, Ljiljana, Bojović, Dragan, "Properties of composite cement with commercial and manufactured metakaolin" in Tehnicki Vjesnik-Technical Gazette, 20, no. 4 (2013):683-687,
https://hdl.handle.net/21.15107/rcub_rims_213 .
2
4

High-temperature concrete binders based on fly ash

Terzić, Anja; Radojević, Zagorka; Miličić, Ljiljana; Pavlović, Ljubica; Stojanović, Jovica

(2013)

TY  - JOUR
AU  - Terzić, Anja
AU  - Radojević, Zagorka
AU  - Miličić, Ljiljana
AU  - Pavlović, Ljubica
AU  - Stojanović, Jovica
PY  - 2013
UR  - http://rims.institutims.rs/handle/123456789/203
AB  - High-temperature concrete binders in which fly ash, as environmentally harmful secondary raw material, is combined with masonry and refractory cement is a new option for reapplication of this coal combustion by-product. In this study, the design of the bonding agents was based on the fly ash from lignite coal combustion process and two types of cement: Portland cement and aluminate cement. Fly ash was applied without any further mechanical or thermal treatment. Mechanical properties of the binders were investigated and subsequently correlated with changes which occurred in the phase composition and microstructure of the agents. Scanning electron microscopy was used in investigation of microstructural changes caused by temperature. X-ray diffraction method was used in monitoring of the mineral phase changes also induced by increasing temperature. The investigations conducted on the bonding agents highlighted presence of good refractory properties and temperature-resistance, and also showed high values of compressive strength. The investigated bonding agents, thus, can be applied in refractory concretes, but also in various types of thermo-insulations.
T2  - Revista Romana de Materiale/ Romanian Journal of Materials
T1  - High-temperature concrete binders based on fly ash
EP  - 275
IS  - 3
SP  - 269
VL  - 43
UR  - https://hdl.handle.net/21.15107/rcub_rims_203
ER  - 
@article{
author = "Terzić, Anja and Radojević, Zagorka and Miličić, Ljiljana and Pavlović, Ljubica and Stojanović, Jovica",
year = "2013",
abstract = "High-temperature concrete binders in which fly ash, as environmentally harmful secondary raw material, is combined with masonry and refractory cement is a new option for reapplication of this coal combustion by-product. In this study, the design of the bonding agents was based on the fly ash from lignite coal combustion process and two types of cement: Portland cement and aluminate cement. Fly ash was applied without any further mechanical or thermal treatment. Mechanical properties of the binders were investigated and subsequently correlated with changes which occurred in the phase composition and microstructure of the agents. Scanning electron microscopy was used in investigation of microstructural changes caused by temperature. X-ray diffraction method was used in monitoring of the mineral phase changes also induced by increasing temperature. The investigations conducted on the bonding agents highlighted presence of good refractory properties and temperature-resistance, and also showed high values of compressive strength. The investigated bonding agents, thus, can be applied in refractory concretes, but also in various types of thermo-insulations.",
journal = "Revista Romana de Materiale/ Romanian Journal of Materials",
title = "High-temperature concrete binders based on fly ash",
pages = "275-269",
number = "3",
volume = "43",
url = "https://hdl.handle.net/21.15107/rcub_rims_203"
}
Terzić, A., Radojević, Z., Miličić, L., Pavlović, L.,& Stojanović, J.. (2013). High-temperature concrete binders based on fly ash. in Revista Romana de Materiale/ Romanian Journal of Materials, 43(3), 269-275.
https://hdl.handle.net/21.15107/rcub_rims_203
Terzić A, Radojević Z, Miličić L, Pavlović L, Stojanović J. High-temperature concrete binders based on fly ash. in Revista Romana de Materiale/ Romanian Journal of Materials. 2013;43(3):269-275.
https://hdl.handle.net/21.15107/rcub_rims_203 .
Terzić, Anja, Radojević, Zagorka, Miličić, Ljiljana, Pavlović, Ljubica, Stojanović, Jovica, "High-temperature concrete binders based on fly ash" in Revista Romana de Materiale/ Romanian Journal of Materials, 43, no. 3 (2013):269-275,
https://hdl.handle.net/21.15107/rcub_rims_203 .
3
3

Evaluation of Lignite Fly Ash for Utilization as Component in Construction Materials

Terzić, Anja; Pavlović, Ljubica; Miličić, Ljiljana

(Taylor & Francis Inc, Philadelphia, 2013)

TY  - JOUR
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
AU  - Miličić, Ljiljana
PY  - 2013
UR  - http://rims.institutims.rs/handle/123456789/211
AB  - Utilization potential of fly ash, as the main residue in the lignite coal combustion in Serbian power plants, was investigated in present study. High production of fly ash represents extreme hazard for environment. Question of storage of this waste material is disclosed. Recycling and reapplication of fly ash in construction materials industry is only economic solution for ongoing problem. Fly ash can be used as a component in cement, mortar, concrete, bricks, and tiles. In this study, characterization of three different Serbian fly ash capacities was used as base for further fly ash utilization possibilities investigation. Investigation of fly ash mineralogical components as well as chemical composition analysis was emphasized. Macroperformance was correlated to the microstructure of fly ash studied by means of XRD and SEM analysis. Furthermore, thermal stability of crystalline phases, content of trace elements, physico-chemical characteristics, and leaching toxicity were tested. Highlight was placed on the determination of the influence of the fly ash grain-size and its microstructure on the performances of the fly-ash-based products. Comparison of Serbian fly ash properties with characteristics of foreign fly ashes led to the presumption that Serbian fly ash has equal if not better characteristics and that it can be reapplied in production of high-value products manufacturing worldwide.
PB  - Taylor & Francis Inc, Philadelphia
T2  - International Journal of Coal Preparation and Utilization
T1  - Evaluation of Lignite Fly Ash for Utilization as Component in Construction Materials
EP  - 180
IS  - 4
SP  - 159
VL  - 33
DO  - 10.1080/19392699.2013.776960
ER  - 
@article{
author = "Terzić, Anja and Pavlović, Ljubica and Miličić, Ljiljana",
year = "2013",
abstract = "Utilization potential of fly ash, as the main residue in the lignite coal combustion in Serbian power plants, was investigated in present study. High production of fly ash represents extreme hazard for environment. Question of storage of this waste material is disclosed. Recycling and reapplication of fly ash in construction materials industry is only economic solution for ongoing problem. Fly ash can be used as a component in cement, mortar, concrete, bricks, and tiles. In this study, characterization of three different Serbian fly ash capacities was used as base for further fly ash utilization possibilities investigation. Investigation of fly ash mineralogical components as well as chemical composition analysis was emphasized. Macroperformance was correlated to the microstructure of fly ash studied by means of XRD and SEM analysis. Furthermore, thermal stability of crystalline phases, content of trace elements, physico-chemical characteristics, and leaching toxicity were tested. Highlight was placed on the determination of the influence of the fly ash grain-size and its microstructure on the performances of the fly-ash-based products. Comparison of Serbian fly ash properties with characteristics of foreign fly ashes led to the presumption that Serbian fly ash has equal if not better characteristics and that it can be reapplied in production of high-value products manufacturing worldwide.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "International Journal of Coal Preparation and Utilization",
title = "Evaluation of Lignite Fly Ash for Utilization as Component in Construction Materials",
pages = "180-159",
number = "4",
volume = "33",
doi = "10.1080/19392699.2013.776960"
}
Terzić, A., Pavlović, L.,& Miličić, L.. (2013). Evaluation of Lignite Fly Ash for Utilization as Component in Construction Materials. in International Journal of Coal Preparation and Utilization
Taylor & Francis Inc, Philadelphia., 33(4), 159-180.
https://doi.org/10.1080/19392699.2013.776960
Terzić A, Pavlović L, Miličić L. Evaluation of Lignite Fly Ash for Utilization as Component in Construction Materials. in International Journal of Coal Preparation and Utilization. 2013;33(4):159-180.
doi:10.1080/19392699.2013.776960 .
Terzić, Anja, Pavlović, Ljubica, Miličić, Ljiljana, "Evaluation of Lignite Fly Ash for Utilization as Component in Construction Materials" in International Journal of Coal Preparation and Utilization, 33, no. 4 (2013):159-180,
https://doi.org/10.1080/19392699.2013.776960 . .
32
23
34

Geopolimeri na bazi alkalno aktiviranog elektrofilterskog pepela kao novo vezivo u betonu

Dragaš, Jelena; Marinković, Snežana; Miličić, Ljiljana; Marković, Smilja; Tošić, Nikola; Ignjatović, Ivan

(Udruženje inženjera građevinarstva, geotehnike, arhitekture i urbanista "Izgradnja", Beograd, 2013)

TY  - JOUR
AU  - Dragaš, Jelena
AU  - Marinković, Snežana
AU  - Miličić, Ljiljana
AU  - Marković, Smilja
AU  - Tošić, Nikola
AU  - Ignjatović, Ivan
PY  - 2013
UR  - http://rims.institutims.rs/handle/123456789/208
AB  - U skladu sa rastućom brigom za zaštitu životne sredine i potrebom razvoja održivog građevinarstva, javlja se i veće interesovanje za istraživanja u oblasti novih materijala, koji će koristiti otpadne sirovine i imati manji uticaj na životnu sredinu. U ovom radu analizirane su karakteristike elektrofilterskog pepela iz termoelektrane 'Nikola Tesla B'u Obrenovcu i mogućnost njegove primene u geopolimerima na bazi alkalno aktiviranog elektrofilterskog pepela, kao novog veziva za beton. Vršena su eksperimentalna ispitivanja granulometrijskog i hemijskog sastava pepela, kao i ugradljivosti i čvrstoće pri pritisku uzoraka spravljenih od geopolimer pasti sa različitim odnosom vodenog stakla i natrijum-hidroksida kao alkalnih aktivatora. Rezultati istraživanja pokazuju da se pepeo iz termoelektrane 'Nikola Tesla B' može upotrebiti kao vezivo u geopolimerima sa vodenim staklom i natrijum-hidroksidom, kao alkalnim aktivatorom uz negu zagrevanjem na 80°C u određenom vremenskom periodu.
AB  - As the concern for the environment and need for sustainable construction practice continues to grow, research in the field of new materials made with waste materials which have a lower impact on the environment is gaining wide interest. This paper analyzes the characteristics of fly ash from power plant 'Nikola Tesla B', and its applications in alkali activated fly ash geopolymers as a new binder in concrete. Testing of the particle size distribution and chemical composition of fly ash has been done, as well as the testing of workability and compressive strength of geopolymer pastes under different ratios of water glass and sodium hydroxide. The results show that fly ash from power plant 'Nikola Tesla B' can be used as a binder in alkali activated fly ash geopolymers made with water glass and sodium hydroxide as alkali activators cured on 80°C a certain period of time.
PB  - Udruženje inženjera građevinarstva, geotehnike, arhitekture i urbanista "Izgradnja", Beograd
T2  - Izgradnja
T1  - Geopolimeri na bazi alkalno aktiviranog elektrofilterskog pepela kao novo vezivo u betonu
T1  - Alkali activated fly ash geopolymers as a new binder in concrete
EP  - 366
IS  - 9-10
SP  - 359
VL  - 67
UR  - https://hdl.handle.net/21.15107/rcub_rims_208
ER  - 
@article{
author = "Dragaš, Jelena and Marinković, Snežana and Miličić, Ljiljana and Marković, Smilja and Tošić, Nikola and Ignjatović, Ivan",
year = "2013",
abstract = "U skladu sa rastućom brigom za zaštitu životne sredine i potrebom razvoja održivog građevinarstva, javlja se i veće interesovanje za istraživanja u oblasti novih materijala, koji će koristiti otpadne sirovine i imati manji uticaj na životnu sredinu. U ovom radu analizirane su karakteristike elektrofilterskog pepela iz termoelektrane 'Nikola Tesla B'u Obrenovcu i mogućnost njegove primene u geopolimerima na bazi alkalno aktiviranog elektrofilterskog pepela, kao novog veziva za beton. Vršena su eksperimentalna ispitivanja granulometrijskog i hemijskog sastava pepela, kao i ugradljivosti i čvrstoće pri pritisku uzoraka spravljenih od geopolimer pasti sa različitim odnosom vodenog stakla i natrijum-hidroksida kao alkalnih aktivatora. Rezultati istraživanja pokazuju da se pepeo iz termoelektrane 'Nikola Tesla B' može upotrebiti kao vezivo u geopolimerima sa vodenim staklom i natrijum-hidroksidom, kao alkalnim aktivatorom uz negu zagrevanjem na 80°C u određenom vremenskom periodu., As the concern for the environment and need for sustainable construction practice continues to grow, research in the field of new materials made with waste materials which have a lower impact on the environment is gaining wide interest. This paper analyzes the characteristics of fly ash from power plant 'Nikola Tesla B', and its applications in alkali activated fly ash geopolymers as a new binder in concrete. Testing of the particle size distribution and chemical composition of fly ash has been done, as well as the testing of workability and compressive strength of geopolymer pastes under different ratios of water glass and sodium hydroxide. The results show that fly ash from power plant 'Nikola Tesla B' can be used as a binder in alkali activated fly ash geopolymers made with water glass and sodium hydroxide as alkali activators cured on 80°C a certain period of time.",
publisher = "Udruženje inženjera građevinarstva, geotehnike, arhitekture i urbanista "Izgradnja", Beograd",
journal = "Izgradnja",
title = "Geopolimeri na bazi alkalno aktiviranog elektrofilterskog pepela kao novo vezivo u betonu, Alkali activated fly ash geopolymers as a new binder in concrete",
pages = "366-359",
number = "9-10",
volume = "67",
url = "https://hdl.handle.net/21.15107/rcub_rims_208"
}
Dragaš, J., Marinković, S., Miličić, L., Marković, S., Tošić, N.,& Ignjatović, I.. (2013). Geopolimeri na bazi alkalno aktiviranog elektrofilterskog pepela kao novo vezivo u betonu. in Izgradnja
Udruženje inženjera građevinarstva, geotehnike, arhitekture i urbanista "Izgradnja", Beograd., 67(9-10), 359-366.
https://hdl.handle.net/21.15107/rcub_rims_208
Dragaš J, Marinković S, Miličić L, Marković S, Tošić N, Ignjatović I. Geopolimeri na bazi alkalno aktiviranog elektrofilterskog pepela kao novo vezivo u betonu. in Izgradnja. 2013;67(9-10):359-366.
https://hdl.handle.net/21.15107/rcub_rims_208 .
Dragaš, Jelena, Marinković, Snežana, Miličić, Ljiljana, Marković, Smilja, Tošić, Nikola, Ignjatović, Ivan, "Geopolimeri na bazi alkalno aktiviranog elektrofilterskog pepela kao novo vezivo u betonu" in Izgradnja, 67, no. 9-10 (2013):359-366,
https://hdl.handle.net/21.15107/rcub_rims_208 .

Prevention of electrofilter ash toxic leaching by embedding in composite materials

Terzić, Anja; Pavlović, Ljubica; Miličić, Ljiljana

(Inženjersko društvo za koroziju, Beograd, 2013)

TY  - JOUR
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
AU  - Miličić, Ljiljana
PY  - 2013
UR  - http://rims.institutims.rs/handle/123456789/201
AB  - Disposal of the fly ash may pose a significant risk to the environment due to the leaching of hazardous pollutants. The only sustainable solution for the pollution-prevention is the reapplication of fly ash as one of the components in construction material composites. There is a risk of leaching even when fly ash is built-in the construction composites and the goal of this investigation was to prove that leaching concentrations of toxic elements is in range assigned by actual regulations. Fly ash was applied in several composits: mortar, concrete and asphalt. The leachability of the potentially toxic elements from the fly ash based products was investigated. The leaching behavior and potential environmental impact of the 11 potentially hazardous elements was tracked: Pb, Cd, Zn, Cu, Ni, Cr, Hg, As, Ba, Sb and Se. A detailed study of physico-chemical characteristics of the fly ash is included. The overall results showed that most of the elements are more readily leachable from the fly ash in comparison with the fly ash based composites.
PB  - Inženjersko društvo za koroziju, Beograd
T2  - Zaštita materijala
T1  - Prevention of electrofilter ash toxic leaching by embedding in composite materials
EP  - 123
IS  - 2
SP  - 117
VL  - 54
UR  - https://hdl.handle.net/21.15107/rcub_rims_201
ER  - 
@article{
author = "Terzić, Anja and Pavlović, Ljubica and Miličić, Ljiljana",
year = "2013",
abstract = "Disposal of the fly ash may pose a significant risk to the environment due to the leaching of hazardous pollutants. The only sustainable solution for the pollution-prevention is the reapplication of fly ash as one of the components in construction material composites. There is a risk of leaching even when fly ash is built-in the construction composites and the goal of this investigation was to prove that leaching concentrations of toxic elements is in range assigned by actual regulations. Fly ash was applied in several composits: mortar, concrete and asphalt. The leachability of the potentially toxic elements from the fly ash based products was investigated. The leaching behavior and potential environmental impact of the 11 potentially hazardous elements was tracked: Pb, Cd, Zn, Cu, Ni, Cr, Hg, As, Ba, Sb and Se. A detailed study of physico-chemical characteristics of the fly ash is included. The overall results showed that most of the elements are more readily leachable from the fly ash in comparison with the fly ash based composites.",
publisher = "Inženjersko društvo za koroziju, Beograd",
journal = "Zaštita materijala",
title = "Prevention of electrofilter ash toxic leaching by embedding in composite materials",
pages = "123-117",
number = "2",
volume = "54",
url = "https://hdl.handle.net/21.15107/rcub_rims_201"
}
Terzić, A., Pavlović, L.,& Miličić, L.. (2013). Prevention of electrofilter ash toxic leaching by embedding in composite materials. in Zaštita materijala
Inženjersko društvo za koroziju, Beograd., 54(2), 117-123.
https://hdl.handle.net/21.15107/rcub_rims_201
Terzić A, Pavlović L, Miličić L. Prevention of electrofilter ash toxic leaching by embedding in composite materials. in Zaštita materijala. 2013;54(2):117-123.
https://hdl.handle.net/21.15107/rcub_rims_201 .
Terzić, Anja, Pavlović, Ljubica, Miličić, Ljiljana, "Prevention of electrofilter ash toxic leaching by embedding in composite materials" in Zaštita materijala, 54, no. 2 (2013):117-123,
https://hdl.handle.net/21.15107/rcub_rims_201 .

Evalution of concretes with standard and recycled raw materials for high temperature application

Terzić, Anja; Pavlović, Ljubica; Radojević, Zagorka; Miličić, Ljiljana

(2012)

TY  - JOUR
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
AU  - Radojević, Zagorka
AU  - Miličić, Ljiljana
PY  - 2012
UR  - http://rims.institutims.rs/handle/123456789/172
AB  - Concrete undergoing thermal treatment before and during life-service can be applied as building material for thermal insulation in high-temperature plants. When such concretes are designed with secondary raw materials they show satisfying performances. Sintering and microstructural changes occur within concrete with increasing temperature. Change progression can be monitored by measuring compressive strength and porosity with destructive and non-destructive tests (ultrasonic pulse velocity technique, image analysis). Experiment has been performed on standard, corundum concrete and recycled, bauxite concrete. Samples were thermally treated from 110 to 1500 degrees C. Destructive tests were used in compressive strength and porosity investigation. Non-destructive tests were performed in order to compare results. Creep testing was conducted to prove sintering process. Results showed that recycled concrete has equal properties as standard concrete.
T2  - Revista Romana de Materiale/ Romanian Journal of Materials
T1  - Evalution of concretes with standard and recycled raw materials for high temperature application
EP  - 151
IS  - 2
SP  - 143
VL  - 42
UR  - https://hdl.handle.net/21.15107/rcub_rims_172
ER  - 
@article{
author = "Terzić, Anja and Pavlović, Ljubica and Radojević, Zagorka and Miličić, Ljiljana",
year = "2012",
abstract = "Concrete undergoing thermal treatment before and during life-service can be applied as building material for thermal insulation in high-temperature plants. When such concretes are designed with secondary raw materials they show satisfying performances. Sintering and microstructural changes occur within concrete with increasing temperature. Change progression can be monitored by measuring compressive strength and porosity with destructive and non-destructive tests (ultrasonic pulse velocity technique, image analysis). Experiment has been performed on standard, corundum concrete and recycled, bauxite concrete. Samples were thermally treated from 110 to 1500 degrees C. Destructive tests were used in compressive strength and porosity investigation. Non-destructive tests were performed in order to compare results. Creep testing was conducted to prove sintering process. Results showed that recycled concrete has equal properties as standard concrete.",
journal = "Revista Romana de Materiale/ Romanian Journal of Materials",
title = "Evalution of concretes with standard and recycled raw materials for high temperature application",
pages = "151-143",
number = "2",
volume = "42",
url = "https://hdl.handle.net/21.15107/rcub_rims_172"
}
Terzić, A., Pavlović, L., Radojević, Z.,& Miličić, L.. (2012). Evalution of concretes with standard and recycled raw materials for high temperature application. in Revista Romana de Materiale/ Romanian Journal of Materials, 42(2), 143-151.
https://hdl.handle.net/21.15107/rcub_rims_172
Terzić A, Pavlović L, Radojević Z, Miličić L. Evalution of concretes with standard and recycled raw materials for high temperature application. in Revista Romana de Materiale/ Romanian Journal of Materials. 2012;42(2):143-151.
https://hdl.handle.net/21.15107/rcub_rims_172 .
Terzić, Anja, Pavlović, Ljubica, Radojević, Zagorka, Miličić, Ljiljana, "Evalution of concretes with standard and recycled raw materials for high temperature application" in Revista Romana de Materiale/ Romanian Journal of Materials, 42, no. 2 (2012):143-151,
https://hdl.handle.net/21.15107/rcub_rims_172 .
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