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Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives

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2023
bitstream_1186.pdf (303.3Kb)
Authors
Mijatović, Nevenka
Terzić, Anja
Miličić, Ljiljana
Article (Published version)
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Abstract
Natural zeolite and bentonite were used as mineral addi-tions to create cement-based building materials that are safe for the environment. This research focuses on the adsorptive qualities of these two clay raw materials, i.e., their propen-sity to immobilize heavy metal ions like Cd2+. The acquired results were examined using kinetic models of pseudo-first and pseudo-second order. The isotherms of Langmuir and Freundlich were examined. Zeolite and bentonite had differ-ent adsorption affinities for Cd2+ cations. Seven cement binders with various mineral additions (fly ash, zeolite, bentonite) underwent a leaching test. The adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites caused leachates obtained on cement samples with the addition of fly ash and clay (either zeolite or bentonite) to contain lower concentrations of Cd2+ ions than leachates obtained on cement samples with fly ash alone.
Keywords:
mineral additives / construction materials / recycling / ion immobilization / leaching control
Source:
Structural Integrity and Life, Special Issue, 2023, 23, 19-24
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200012 (Istitute of Material Testing of Serbia - IMS, Belgrade) (RS-200012)

ISSN: 1451-3749

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_rims_488
URI
http://rims.institutims.rs/handle/123456789/488
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
Institut za ispitivanje materijala
TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Miličić, Ljiljana
PY  - 2023
UR  - http://rims.institutims.rs/handle/123456789/488
AB  - Natural zeolite and bentonite were used as mineral addi-tions to create cement-based building materials that are safe for the environment. This research focuses on the adsorptive qualities of these two clay raw materials, i.e., their propen-sity to immobilize heavy metal ions like Cd2+. The acquired results were examined using kinetic models of pseudo-first and pseudo-second order. The isotherms of Langmuir and Freundlich were examined. Zeolite and bentonite had differ-ent adsorption affinities for Cd2+ cations. Seven cement binders with various mineral additions (fly ash, zeolite, bentonite) underwent a leaching test. The adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites caused leachates obtained on cement samples with the addition of fly ash and clay (either zeolite or bentonite) to contain lower concentrations of Cd2+ ions than leachates obtained on cement samples with fly ash alone.
T2  - Structural Integrity and Life, Special Issue
T1  - Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives
EP  - 24
SP  - 19
VL  - 23
UR  - https://hdl.handle.net/21.15107/rcub_rims_488
ER  - 
@article{
author = "Mijatović, Nevenka and Terzić, Anja and Miličić, Ljiljana",
year = "2023",
abstract = "Natural zeolite and bentonite were used as mineral addi-tions to create cement-based building materials that are safe for the environment. This research focuses on the adsorptive qualities of these two clay raw materials, i.e., their propen-sity to immobilize heavy metal ions like Cd2+. The acquired results were examined using kinetic models of pseudo-first and pseudo-second order. The isotherms of Langmuir and Freundlich were examined. Zeolite and bentonite had differ-ent adsorption affinities for Cd2+ cations. Seven cement binders with various mineral additions (fly ash, zeolite, bentonite) underwent a leaching test. The adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites caused leachates obtained on cement samples with the addition of fly ash and clay (either zeolite or bentonite) to contain lower concentrations of Cd2+ ions than leachates obtained on cement samples with fly ash alone.",
journal = "Structural Integrity and Life, Special Issue",
title = "Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives",
pages = "24-19",
volume = "23",
url = "https://hdl.handle.net/21.15107/rcub_rims_488"
}
Mijatović, N., Terzić, A.,& Miličić, L.. (2023). Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives. in Structural Integrity and Life, Special Issue, 23, 19-24.
https://hdl.handle.net/21.15107/rcub_rims_488
Mijatović N, Terzić A, Miličić L. Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives. in Structural Integrity and Life, Special Issue. 2023;23:19-24.
https://hdl.handle.net/21.15107/rcub_rims_488 .
Mijatović, Nevenka, Terzić, Anja, Miličić, Ljiljana, "Effective removal of the heavy metal ion Cd2+ from the structure of cementitious materials with mineral additives" in Structural Integrity and Life, Special Issue, 23 (2023):19-24,
https://hdl.handle.net/21.15107/rcub_rims_488 .

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